Chemistry Final
Physical Changes
Changes without changing its chemical composition
(condense, freeze, melt, dissolve, grin, change in state)
Chemical Changes
When 1 or more substances change into new substances
Chemical compostion changes
Chemical Reaction
(change in odor, gas, precipitate, energy light, heat, color change)
Physical Property
observed without changing chemical compostion
(boiling point, melting point, solubility, color, odor, hardness, density)
Chmical property
ability to undergo a chem reaction
(flammable, rusting, not reacting)
Law of conservation of mass
matter is neither created no destroyed
Elements
a pure substance that can not be broken down into simpler substances
Compounds
pure substance made from atoms of 2 or more different elements that are chemically bonded (H20)
Dalton's Atomic Theory
1. All matter is made of atoms that are indivisible and indestructible
2. All atoms of a given element are identical in mass and properties
3. Compounds are formed by a combo of 2 or more different kinds of atoms
4. Chemical reactions rearrange atoms
Structure of an Atom
Nucleus: Made of protons and neutrons (In the center)
Electrons: Orbit around the nucleus in specific energy levels
Godl foil Experiment
ERnest Rutherford shot positively charged particles (alpha particles) at a thin piece of foil and some went right through while some reflected back
Conclusions:1. most of an atom is empty space 2. atoms have a nucleus (small dense core with a positvie charge)
# of protons=
atomic # and # of electrons
atomic # =
# protons and # electrons
Mass #=
# protons + # neutrons
Isotopes
forms of the same atom that vary in mass and have a different number of neutrons (common to al elements-not all natural)
Hyphen Notation
Cu-63 (63=mass)
Nuclear Symbol
63 CU
29 (63= mass 29 = atomic #)
Quantum Mechanical Model
(Schrodinger) Quantum- the amount of energy required to move an electron from its present energy level to the nest higher one
-Mathematical formula to describe the probability of finding electrons within a certain space
Energy level
(Floors) region aroudn teh nucleus where the electron is likely to be moving n= 1, 2, 3, 4, etc
Sublevels
(Rooms) each energy level is broken up into sublevels
# of sublevels= # of quantum for that energy level
Orbitals
(Beds) 2 electrons per bed
S-Spherical shaped
P-Dumbell Shaped
D-Clover shaped
F-too complex
Democritus
believed that matter was composed of atoms based on mental reasoning
John Dalton
believed atoms were solid and indivisible mass based on research
J.J Thomson
(plum pudding)discovered the electron, electrons stuck into a lump of positively charged material- didnt know specifics
Ernest Rutherford
Most of an atoms mass is concentrated in a small positively charged region called the nucleus
Neils Bohr
electrons orbit around the nucleus
Quantum Mechanical
Erwin Shrodinger- based on math- where the electrons are located
DeChancourtois
fully functioning periodic table on a cylinder
Canizaro
atomic mass
Mendeleyev
periodic table
Mosley
arranged table based on mass
Seaborg
Final version of the table
Light
Little packets of photons
Wavelength (h)
Visible light ahs a h of 700-750 nm
1nm = 1 x 10-9 m
Frequency
v
Velocity (C)
C=hv
Light travels throgh space at 3.00 * 108 m/s
Calculating energy of a photon
E=Hv
E= energy
H- Plancks constant= 6.662 * 10-34 Js
v= frequency
Brightness of a light depends on...
Amplitude
Ionization energy
energy required to remvoe an electron from an ion or atom
Electronegativity
low to high
amount of pull that an atom's nucleus exerts on another atom's electrons when they are bonded
Atomic Radius
an atom's size depending on the volume occupied by electrons around the nucleus
Octet Rule
atoms will have 8 valence elctrons
Chemical Bond
bodnign together of atoms due to an electrical attraction between the nuclei and valence elctrons (ionic and covalent)
Ionic bonds
attraction of ions in which atoms completely give up electrons to other atoms (cations+anions)
Ionic compound
combination of a metal cation and a non-metal anion in order to establish a stable, neutral compound
Cation
Positive charge (metals)
Anions
Negative charge (nonmetals)
Monoatomic Ion
Made up of one type of atom
Polyatomic Ion
Tightly bound group of atoms that act as a whole and have a charge- NH4
Calculating cation charge
1.Find the charge of the anion
2. Multiply the charge of anion by the subscript of the anion
3. Divide by the subscript on the cation
Covalent compounds
bonds form so atoms can be stable
Covalent bonds
forms from the sharing of one or more pairs of electrons
Non-polar covalent
Bonding electrons are being shared equally between the bonded atoms
polar covalent
shared pair of electrons is held more closely by one fo the atoms
-electrons closer to atom with higher electronegativity
Dipole
a molecule that has a positvie end and a negative end
Lewis Dot structure
Add together total number of valence electrons
Avogadros #
1 mole = 6.022 * 10 23
Molar Mass
mass in grams of 1 mole of a substance
Percent composition
Molar Mass of element *10
Molar mass of compound
Empirical formula
shows the simplest ration for elements
1. Conver % to grams
2. Convert grams to mol
3. Subscripts to whole number (divide by lowest)
(If its still not whole number mulitply by whole numbers)
Molecular formula
a whole number multipe of an empirical formula
Synthesis
A+B= AB
Decompostion
AB = A + B
Single Displacement
AB + M = MB + A
Double Displacement
AB + CD = AD + BC
Combustion
CxHyO2 = CO2 + H20
Diatomic
Br I N Cl H O F
Stoichiometry
use of reactatnts and products to perform calculations
Actual yield
measured amount of a product obtaienc from a reaction
Theoretical
max amount of product that can be produced in a given reaction
Limiting Reactant
1.convert both reactants to grams of the same product
2. Identify the L.R (one that produces least amount of product)
Kinetic Molecular Theory
1. used to predict gas behavior
2. states gas particles are in constant motion
Solvent
dissolving medium
Soute
what is being dissolved
Hydrogen Bond
bond between hydrogen and dipole
London dispersion
al the electrons are on one side and it is a temporary dipole
Dipole-dipole
like a battery
Heterogeneous Mixture
not uniform throughout, composed of dissimilar things, can be seperated
Homogeneous Mixture
uniform composition or structure throughout, same proportions throught can not be filtered
Suspension
particles are initially dispersed but will eventually settle out (Hetero)
Solution
Particles are dispersed throughout (homo)
Colloid
gas dispersed in liquid (particles are intermediate in size betweeen those of solutions and suspensions (S, L, G)
Electrolyte
a substance that dissolves in a liquid solvent and provides ions that conduct electricity
non-electrolyte
does not allow an electric curret to move through (no ions)
Saturated
Can not dissolve any more solute under conditions
Unsaturated
solution with less solute then the saturated solution-can dissolve more
Super Saturated
A soluton with more dissolved solute than a saturated and cannot dissolve more
Boiling Point Elevation
dissolved salt raises the boiling point causing water to boil at a higher temp
Freezing Point Depression
dissolved salt lowers the freezing point
Colligative Property
a property of a substance that is determined by the number of particles present in the system but independent of the properties of the particles themselves- the degree of the effect depends on the concentration
Reversible Reactions
products reform into the original reactants
Neutralization
Occurs when H30 and OH react to rofm H20 and salt
Equivalence Point
point at which neutralization reaction is complete
Titration
gradual additon of one solution to another reach teh equivalence point
self ionization
when a pair of H20 molecules are in equilibrium