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Central Science: Chapter 24

front 1

Which substance would be the most soluble in gasoline?
A) water
B) NaNO3
C) HCl
D) hexane
E) NaCl

back 1

D

front 2

If each of the following represents an alkane, and a carbon atom is located at each vertex with the proper number of hydrogen atoms also bonded to it, which one is the most reactive?

back 2

D

front 3

Which of the following is not currently used as an additive agent in gasoline?
A) toluene
B) ethanol
C) MTBE
D) tetraethyl lead

back 3

D

front 4

How many isomers are possible for C4H10?
A) 1
B) 2
C) 3
D) 4
E) 10

back 4

B

front 5

How many isomers are possible for C5H12?
A) 1
B) 2
C) 3
D) 4
E) 10

back 5

C

front 6

The structure of 2,3-dimethylheptane is ________.

back 6

D

front 7

When petroleum is distilled to separate the components by boiling point, the component with the highest boiling point is called ________.
A) gas
B) gasoline
C) kerosene
D) paraffin
E) asphalt

back 7

E

front 8

What type of compound has been used to replace tetraethyl lead (( Pb) as an antiknock agent in gasoline?
A) aromatic compounds
B) olefins
C) fluorochlorocarbons
D) paraffins
E) oxygenated hydrocarbons

back 8

E

front 9

How many structural isomers (include all types except optical) can be drawn for C5H10?
A) 5
B) 6
C) 7
D) 10
E) 12

back 9

D

front 10

How many isomers of C2H2Br2 are polar?
A) none
B) 2
C) 1
D) 3
E) It is impossible to tell without more information.

back 10

B

front 11

Which statement about hydrocarbons is false?
A) The smallest alkane to have structural (constitutional) isomers has 4 carbon atoms.
B) Cyclic alkanes are structural isomers of alkenes.
C) Alkanes are more reactive than alkenes.
D) Alkanes can be produced by hydrogenating alkenes.
E) Alkenes can be polymerized.

back 11

C

front 12

Which statement about addition reactions between alkenes and HBr is false?
A) The addition occurs at the double bond.
B) Bromine attacks the alkene carbon atom possessing a partial positive charge.
C) A hydrogen atom attaches to the alkene carbon atom possessing a partial negative charge.
D) The π bond breaks in the course of the reaction.
E) The proposed mechanism involves radicals.

back 12

E

front 13

Benzene behaves differently from a hydrocarbon which simply contains three C C bonds in that the latter would be expected to react much more readily with ________.
A) H2
B) Cl2
C) Br2
D) HCl
E) all of the above

back 13

E

front 14

Alcohols are hydrocarbon derivatives in which one or more hydrogens have been replaced by a hydroxyl functional group. ________ is the general formula of an alcohol.
A) R—O—R
B) R—CO—R
C) R—CO—OH
D) R—OH
E) R—CO—H

back 14

D

front 15

Which one of the following is not an alcohol?
A) acetone
B) glycerol
C) ethanol
D) cholesterol
E) ethylene glycol

back 15

A

front 16

The oxidation of ethanol produces ________.
A) acetic acid
B) formic acid
C) citric acid
D) lactic acid
E) oxalic acid

back 16

A

front 17

Which one of the following compounds is an isomer of CH3CH2CH2CH2OH?

back 17

D

front 18

Which of the following compounds do not contain an sp3 hybridized oxygen atom?
A) ketones
B) alcohols
C) ethers
D) esters
E) water

back 18

A

front 19

Of the compounds below, ________ is an isomer of [see image]

back 19

front 20

Which structure below represents a ketone?

back 20

front 21

Which structure below represents an amine?

back 21

front 22

Which structure below represents an aldehyde?

back 22

C

front 23

Which structure below represents an ether?

back 23

A

front 24

Which structure below is not correctly drawn?

back 24

B

front 25

All of the following are achiral except ________ which is a chiral molecule.

back 25

B

front 26

How many chiral carbon atoms does the neopentane (2, 2 - dimethylpropane) have?
A) 0
B) 1
C) 2
D) 3
E) 4

back 26

A

front 27

How many chiral centers are there in CH3CHClCH2Cl?
A) 1
B) 0
C) 3
D) 2
E) 4

back 27

A

front 28

Proteins are biopolymers formed via multiple condensation coupling of which two functional groups?
A) ester and amine
B) amine and carboxylic acid
C) alcohol and carboxylic acid
D) alcohol and amine
E) ester and carboxylic acid

back 28

B

front 29

Which amino acid is not chiral?
A) leucine
B) isoleucine
C) glycine
D) alanine
E) threonine

back 29

C

front 30

The tertiary structure of proteins is maintained by ________ bonds.
A) hydrogen
B) dipole-dipole
C) ion-dipole
D) covalent
E) all of the above

back 30

E

front 31

Which of the following contains a peptide linkage?

back 31

A

front 32

Sugars are examples of what type of molecule?
A) proteins
B) carbohydrates
C) nucleic acids
D) amino acids
E) salts

back 32

B

front 33

The principal difference between fructose and glucose is that ________.
A) fructose is a disaccharide and glucose is a monosaccharide
B) fructose is a monosaccharide and glucose is a disaccharide
C) fructose is chiral and glucose is not
D) glucose is chiral and fructose is not
E) fructose is a ketone sugar and glucose is an aldehyde sugar

back 33

E

front 34

Which one of the following is a monosaccharide?
A) fructose
B) lactose
C) sucrose
D) maltose
E) none of the above

back 34

A

front 35

Consider the following types of compounds:
(i) amino acid
(ii) nitrogen-containing organic base
(iii) phosphoric acid
(iv) five-carbon sugar

From which of the above compounds are the monomers of nucleic acids, called nucleotides, formed?
A) none
B) (i) and (ii)
C) (ii) and (iv)
D) (ii), (iii), and (iv)
E) all

back 35

D

front 36

The basic building block of nucleic acids is the ________.
A) nucleoside
B) nucleotide
C) ester linkage
D) nitrogen base
E) phosphoric acid

back 36

B

front 37

The double helix of DNA is stabilized mainly by ________.
A) ionic bonds
B) covalent bonds
C) ion-dipole bonds
D) ester bonds
E) hydrogen bonds

back 37

E

front 38

Hybridization of the carbon atom indicated by (*) in CH3-*CH2-CH3, *CH2 CH2, and CH3-*C≡CH is ________, ________, and ________, respectively.
A) sp3, sp2, sp
B) sp3, sp, sp2
C) sp, sp2, sp3
D) sp, sp3, sp2
E) sp2, sp3, sp

back 38

A

front 39

Hydrocarbons containing only single bonds between the carbon atoms are called ________.
A) alkenes
B) alkynes
C) aromatics
D) alkanes
E) ketones

back 39

D

front 40

What general class of compounds is also known as olefins?
A) alkenes
B) alkynes
C) aromatics
D) alkanes
E) ketones

back 40

A

front 41

The simplest alkyne is ________.
A) ethylene
B) ethane
C) acetylene
D) propyne
E) benzene

back 41

C

front 42

The melting and boiling points of hydrocarbons are determined by ________.
A) ion-dipole attraction
B) dipole-dipole attraction
C) London forces
D) hydrogen bonding
E) ionic bonding

back 42

C

front 43

Hydrocarbons containing carbon-carbon triple bonds are called ________.
A) alkanes
B) aromatic hydrocarbons
C) alkynes
D) alkenes
E) olefins

back 43

C

front 44

Alkynes always contain a ________.
A) C=C bond
B) C≡C bond
C) C—C bond
D) C=H bond
E) C≡H bond

back 44

B

front 45

Alkenes always contain a ________.
A) C=C bond
B) C≡C bond
C) C-C bond
D) C=H bond
E) C≡H bond

back 45

A

front 46

The molecular geometry of each carbon atom in an alkane is ________.
A) octahedral
B) square planar
C) trigonal planar
D) tetrahedral
E) trigonal pyramidal

back 46

D

front 47

The minimum number of carbons necessary for a hydrocarbon to form a branched structure is ________.
A) 4
B) 6
C) 3
D) 9
E) 12

back 47

A

front 48

Cyclohexane has ________ fewer hydrogens than n-hexane.
A) 0
B) 1
C) 2
D) 3
E) 4

back 48

C

front 49

How many structural isomers of heptane exist?
A) 2
B) 4
C) 6
D) 8
E) 9

back 49

E

front 50

The general formula of an alkane is ________.
A) C2nH2n+2
B) CnH2n
C) CnH2n+2
D) CnH2n-2
E) CnHn

back 50

C

front 51

Alkanes with ________ to ________ carbons are found in straight-run gasoline.
A) 2, 3
B) 5, 12
C) 1, 5
D) 9, 15
E) 20, 60

back 51

B

front 52

Gasoline and water do not mix because gasoline is ________.
A) less dense than water
B) less viscous than water
C) nonpolar and water is polar
D) volatile and water is not
E) polar and water is nonpolar

back 52

C

front 53

Isooctane is assigned an octane number of 100, whereas ________ is assigned an octane number of 0.
A) methane
B) propane
C) benzene
D) heptane
E) nitrous oxide

back 53

D

front 54

The octane number of straight-run gasoline is about ________.
A) 0
B) 25
C) 50
D) 75
E) 93

back 54

C

front 55

Alkenes have the general formula ________.
A) CnH2n
B) CnH2n-2
C) CnH2n+2
D) CnHn
E) C2nHn

back 55

A

front 56

The compound below is an ________.

H2C=CH—CH3

A) alkyne
B) alkene
C) alkane
D) aromatic compound
E) olefin

back 56

B

front 57

What is the name of the compound below?

A) 2,4-methylbutene
B) 2,5-dimethylpentane
C) 2,4-ethylbutene
D) 2,4-dimethyl-1-pentene
E) 2,4-dimethyl-4-pentene

back 57

D

front 58

The name of CH3-CH=C=CH-CH-CH=CH-CH3 is ________.
A) 2, 3, 5 - octatriene
B) 2, 5, 6 - octatriene
C) 2, 3, 6 - octatriene
D) 3, 5, 6 - octatriene
E) 3, 4, 7 - octatriene

back 58

C

front 59

________ could be the formula of an alkene.
A) C3H8
B) C3H6
C) C6H6
D) C17H36
E) CH8

back 59

B

front 60

In general, ________ are the least reactive hydrocarbons.
A) alkenes
B) alkynes
C) alkanes

back 60

C

front 61

The addition of HBr to 2-butene produces ________.
A) 1-bromobutane
B) 2-bromobutane
C) 1,2-dibromobutane
D) 2,3-dibromobutane
E) no reaction

back 61

B

front 62

________ contains a series of π bonds on several consecutive carbon atoms.
A) pentane
B) cyclohexane
C) benzene
D) hexane

back 62

C

front 63

How many hydroxyl groups are in a glycerol molecule?
A) 0
B) 1
C) 2
D) 3
E) 4

back 63

D

front 64

The general formula for an ether is ________.

back 64

A

front 65

Ethers can be made by condensation of two ________ molecules by splitting out a molecule of water.
A) alkyne
B) alcohol
C) ketone
D) aldehyde
E) olefin

back 65

B

front 66

The general formula of an aldehyde is ________.

back 66

E

front 67

The general formula of a carboxylic acid is ________.

back 67

C

front 68

The general formula of an ester is ________.

back 68

E

front 69

is called a(n) ________.
A) amine
B) amide
C) ketone
D) aldehyde
E) ester

back 69

B

front 70

The compound below is a(n) ________.

A) carboxylic acid
B) ketone
C) aldehyde
D) ester
E) amine

back 70

D

front 71

The hybridization of the central carbon atom in formaldehyde is ________.
A) sp
B) sp3
C) d2sp3
D) sp2
E) sp4

back 71

D

front 72

Optically active molecules that are mirror images of each other are called ________.
A) allotropes
B) geometrical isomers
C) enantiomers
D) cofactors
E) chiral compounds

back 72

C

front 73

The secondary structure of a protein is the result of ________ bonding.
A) covalent
B) peptide
C) ionic
D) hydrogen
E) none of the above

back 73

D

front 74

Starch, glycogen, and cellulose are made of repeating units of ________.
A) lactose
B) glucose
C) fructose
D) sucrose
E) amino acids

back 74

B

front 75

How many chiral atoms does the open-chain form of glucose have?
A) 1
B) 2
C) 3
D) 4
E) 5

back 75

D

front 76

________ acts as a kind of energy bank in the body, and is found concentrated in muscles and liver.
A) Lactose
B) Starch
C) Cellulose
D) Glycogen
E) Sucrose

back 76

D

front 77

What forces hold the strands of DNA together?
A) covalent bonds
B) hydrogen bonding
C) ion-dipole attraction
D) coordinate covalent bonds

back 77

B

front 78

Which one of the following could be a straight-chain alkane?
A) C9H20
B) C3H3
C) C4H6
D) C5H4
E) C3H6

back 78

A

front 79

Which one of the following could be a non-branched alkene?
A) C6H5
B) C7H9
C) C7H14
D) C2H6
E) C9H20

back 79

C

front 80

Which one of the following could be a cycloalkane?
A) C6H5
B) C3H5
C) C2H6
D) C10H22
E) C5H10

back 80

E

front 81

Pentane has ________ structural isomers.
A) 3
B) 2
C) 1
D) 4
E) 5

back 81

A

front 82

What geometric shape will the structure of cyclohexane appear as when drawn as a line structure?
A) hexagon
B) heptagon
C) octagon
D) triangle
E) square

back 82

A

front 83

Gas, isolated from petroleum, has a minimum of ________ carbon atoms.
A) 1
B) 36
C) 20
D) 16
E) 12

back 83

A

front 84

The correct name for the molecule CH3CH3 is ________.
A) ethane
B) propane
C) ethyl
D) propyne
E) butaneA

back 84

A

front 85

In an addition reaction, H2 is added to 1-propene in the presence of a nickel catalyst to form ________.
A) propanol
B) propyne
C) propane
D) 2-butene
E) propanoic acid

back 85

C

front 86

Primary alcohols can be oxidized to produce ________.
A) amides
B) esters
C) aldehydes
D) secondary alcohols
E) amines

back 86

C

front 87

What is the general formula for an aldehyde?

back 87

A

front 88

All of the following contain a C=O bond except ________.
A) aldahydes
B) carboxylic acids
C) alcohols
D) esters
E) none of the above

back 88

C

front 89

The suffix used for organic molecules containing the ketone functional group is ________.
A) -one
B) -oic acid
C) -oate
D) -amide
E) -ene

back 89

A

front 90

How many chiral centers are there in CH3CHCHCH2CHBr2?
A) 0
B) 1
C) 2
D) 3
E) 4

back 90

A

front 91

________ is a disaccharide.
A) Sucrose
B) Fructose
C) Ribose
D) Cellulose
E) UracilA

back 91

A

front 92

________ is a monosaccharide.
A) Fructose
B) Lactose
C) Guanine
D) Glycogen
E) none of the above

back 92

A

front 93

________ is a polysaccharide.
A) Cellulose
B) Galactose
C) Ribose
D) Sucrose
E) Uracil

back 93

A

front 94

What is the electron group geometry surrounding the carbon atoms in alkanes?

back 94

tetrahedral

front 95

The resistance of gasoline to engine knocking is referred to as its ________.

back 95

octane number or octane rating

front 96

Why is cyclopropane more reactive than propane?

back 96

The small ring of cyclopropane forces the C-C-C bond angle to be significantly less than the 109.5° bond angle of C within the tetrahedral structure of propane.

front 97

What is the name of the compound below?

back 97

4-propyloctane

front 98

Write the formula for 2-methyl-4-propylnonane.

back 98

front 99

What is the correct name for the compound, Ch3CH=CHCh2CH=CHCH3?

back 99

2,2-heptadiene

front 100

What is the name of the compound below?

back 100

4,6-dimethyl-1-heptyne

front 101

Hydrogenation of an alkene requires high temperatures and a catalyst such as nickel. Why is this?

back 101

due to the large bond enthalpy of H2

front 102

Predict the product of the catalytic hydrogenation of 6-ethyl-3-decene.

back 102

6-ethyldecane

front 103

Hydrogenation of what alkyne produces propane?

back 103

propyne

front 104

In the reaction of nitric acid with benzene, which isomer is formed when a second nitro group is substituted?

back 104

meta

front 105

The addition of an alkyl halide to an aromatic ring compound is called the ________ reaction.

back 105

Friedel-Crafts

front 106

The anaerobic conversion of carbohydrates to ethanol is driven by the presence of ________.

back 106

yeast

front 107

What is the name of the compound CH3CH2CH(OH)CH2CH2CH3?

back 107

3-hexanol

front 108

The formation of aspirin by reacting salicylic acid with acetic acid is a(n) ________ reaction.

back 108

condensation

front 109

In the oxidation of ethanol the intermediate formed is ________.

back 109

acetaldehyde

front 110

The primary ingredient in vinegar is ________.

back 110

acetic acid

front 111

The aromas of different fruit are due to the chemical compounds known as ________.

back 111

esters

front 112

The hydrolysis of an ester in the presence of a base is called ________.

back 112

saponification

front 113

Non-superimposable mirror-image isomers of a substance are called ________.

back 113

enantiomers

front 114

Living organisms must expend energy to counter any increase in ________.

back 114

entropy

front 115

The doubly ionized form of an amino acid is called a(n) ________.

back 115

zwitterion

front 116

Of the 20 amino acids found in our bodies, ________ of them must be ingested because our bodies cannot synthesize sufficient quantities of them.

back 116

10

front 117

Large protein molecules that act as catalysts are called ________.

back 117

enzymes

front 118

The most important acidic and basic functional groups in all amino acids are the ________ and the ________ groups, respectively.

back 118

carboxylic acid, amino

front 119

The condensation reaction of a carboxyl group of one amino acid and the amino group of a second amino acid results in the formation of a(n) ________.

back 119

peptide bond

front 120

Lactose is a disaccharide of glucose and ________.

back 120

galactose

front 121

The monomers of nucleic acids, called nucleotides, consist of three parts. These are ________.

back 121

phosphoric acid, a five-carbon sugar, and a nitrogen-containing organic base

front 122

In DNA, adenine is always paired with ________.

back 122

thymine

front 123

The overall polarity of organic molecules is high.

back 123

false

front 124

Cyclobutane is more reactive than butane.

back 124

true

front 125

The stability of benzene is a major function of delocalized π bonding.

back 125

true

front 126

Aldehydes are less reactive than ketones.

back 126

false

front 127

A carbon with three or more attached groups will be chiral.

back 127

false

front 128

Racemic mixtures of enantiomers do not rotate the plane of polarized light.

back 128

true

front 129

The majority of glucose molecules exist in ring structure.

back 129

true

front 130

Humans digest starch but not cellulose because of differences in the type of linkage between the glucose monomers of these substances.

back 130

true

front 131

The DNA double helix is held together by hydrogen bonds and London dispersion forces.

back 131

true