CHEM 23: Statistics and Data Handling in Analytical Chemistry Flashcards


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UP Cebu - Chem 23 Statistics and Data Handling in Analytical Chemistry
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chemistry 23
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low accuracy, low precision

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low accuracy, high precision

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high accuracy, low preicison

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high accuracy, high precision

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accuracy

agreement between a measured value and the accepted true value, how close would it be to the actual value

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ways to express accuracy

absolute error and relative error

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absolute error formula

measured value – true value

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relative error formula

((measured value - true value)/(true value)) x 100%

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precision

degree of agreement between replicate measurements of the same quantity

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determinate errors

determinable and that presumably can be either avoided or corrected

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instrumental errors

faulty equipment

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example of instrumental error

uncalibrated glassware

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operative errors

personal errors

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example of operative error

mathematical error in calculation, misread of menisicus

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errors of the method

wrong method for an experiment

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example of error of the method

coprecipitation of impurities

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indeterminate errors

accidental or random errors

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what does indeterminate error show in a distribution?

bell curve or normal distribution

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significant figures

the number of digits necessary to express the results of a measurement consistent with the measured precision

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significant figure rule in addition and subtraction

use least significant decimal place

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significant figure rule in multiplication and division

use least significant figures