Chapter 16
Which solution below has the highest concentration of hydronium ions?Answers:
pH = 3.0
pH = 10
pH = 7.0
pH = 6.4
pH = 11.2
Selected Answer:
pH = 3.0
Ammonia is a ________.
Answers:
weak acid
strong base
weak base
strong acid
salt
Selected Answer: weak base
Classify the following compounds as weak acids (W) or strong acids (S):
hypochlorous acid perchloric acid chloric acid
Answers:
W S S
S S S
S W W
W W W
W S W
Selected Answer:
W S S
Which of the following ions will act as a weak base in water?
Answers:
HS-
F-
NO2-
ClO-
All of the above will act as a weak base in water.
Selected Answer:
All of the above will act as a weak base in water.
What is the conjugate acid of NH3?
Answers:
NH3
NH2+
NH3+
NH4+
NH4OH
Selected Answer:
NH4+
What is the pH of an aqueous solution at 25.0 °C in which [OH-] is 0.0030 M?
Answers:
5.81
-11.48
2.52
-2.52
11.48
Selected Answer:
11.48
What is the pOH of an aqueous solution at 25.0 °C in which [OH-] is 0.0010 M?
Answers:
11
-3
3
-116.91
Selected Answer:
3
What is the conjugate acid of CO32- ?
Answers:
CO22-
HCO22-
H2CO3
HCO3-
none of the above
Selected Answer:
HCO3-
The pH of a 0.55 M aqueous solution of hypobromous acid, HBrO, at 25.0 °C is 4.48. What is the value of Ka for HBrO?
Answers:
2.0 × 10-9
1.1 × 10-9
6.0 × 10-5
3.3 × 10-5
3.0 × 104
Selected Answer:
2.0 × 10-9
An aqueous solution of ________ will produce a neutral solution.
Answers:
LiNO3
NaNO2
KF
Rb2CO3
NH4NO3
Selected Answer:
LiNO3
Calculate the pOH of 0.606 M anilinium hydrochloride (C6H5NH3Cl) solution in water, given that Kb for aniline is 3.83 × 10-4.
Answers:
1.82
12.18
5.40
8.60
12.42
Selected Answer:
8.60
Of the following substances, an aqueous solution of ________ will form basic solutions.
NaHS Cu(NO3)2 KHCO3 NaF
Answers:
NaHS, Cu(NO3)2
KHCO3, NaHS
NaF only
NaF, KHCO3
NaHS, KHCO3 and NaF
Selected Answer:
NaHS, KHCO3 and NaF
The Ka for HCN is 4.9 × 10-10. What is the value of Kb for CN-?
Answers:
2.0 × 10-5
4.0 × 10-6
4.9 × 104
4.9 × 10-24
2.0 × 109
Selected Answer:
2.0 × 10-5
Which one of the following is the weakest acid?
Answers:
HF (Ka = 6.8 × 10-4)
HClO (Ka = 3.0 × 10-8)
HNO2 (Ka = 4.5 × 10-4)
HCN (Ka = 4.9 × 10-10)
Acetic acid (Ka = 1.8 × 10-5)
Selected Answer:
HCN (Ka = 4.9 × 10-10)
What is the pH of an aqueous solution at 25.0 °C that contains 3.98 × 10-9 M hydronium ion?
Answers:
8.400
5.600
9.000
3.980
7.000
Selected Answer:
8.400
Determine the pH of a 0.15 M aqueous solution of KF. For hydrofluoric acid, Ka = 7.0 × 10-4.
Answers:
0.82
5.83
8.17
5.01
1.17
Selected Answer:
8.17
According to the Arrhenius concept, an acid is a substance that ________.
Answers:
is capable of donating one or more H+
causes an increase in the concentration of H+ in aqueous solutions
can accept a pair of electrons to form a coordinate covalent bond
reacts with the solvent to form the cation formed by autoionization of that solvent tastes bitter
Selected Answer:
causes an increase in the concentration of H+ in aqueous solutions
HZ is a weak acid. An aqueous solution of HZ is prepared by dissolving 0.020 mol of HZ in sufficient water to yield 1.0 L of solution. The pH of the solution was 4.93 at 25.0 °C. The Ka of HZ is ________.
Answers:
1.2 × 10-5
6.9 × 10-9
1.4 × 10-10
9.9 × 10-2
2.8 × 10-12
Selected Answer:
6.9 × 10-9
Which solution will be the most basic?
Answers:
0.10 M Ba(OH)2
0.10 M KOH
0.10 M H2O
0.10 M CH3OH
Selected Answer:
0.10 M Ba(OH)2
Which one of the following statements regarding Kw is false?
Answers:
pKw is 14.00 at 25 °C.
The value of Kw is always 1.0 × 10-14.
Kw changes with temperature.
The value of Kw shows that water is a weak acid.
Kw is known as the ion product of water.
Selected Answer:
The value of Kw is always 1.0 × 10-14.
Which of the following aqueous solutions has the lowest [OH-]?
Answers:
a solution with a pH of 3.0
a 1 × 10-4 M solution of HNO3
a solution with a pOH of 12.0
pure water
a 1 × 10-3 M solution of NH4Cl
Selected Answer:
a solution with a pOH of 12.0
The pH of a 0.25 M aqueous solution of hydrofluoric acid, HF, at 25.0 °C is 2.03. What is the value of Ka for HF?
Answers:
2.0 × 10-9
1.1 × 10-9
6.0 × 10-5
3.5 × 10-4
Selected Answer:
3.5 × 10-4
Of the following substances, an aqueous solution of ________ will form basic solutions.
NH4Cl Cu(NO3)2 K2CO3 NaF
Answers:
NH4Cl, Cu(NO3)2
K2CO3, NH4Cl
NaF only
NaF, K2CO3
NH4Cl only
Selected Answer:
NaF, K2CO3
Calculate the concentration (in M) of hydronium ions in a solution at 25.0 °C with a pOH of 4.223.
Answers:
5.98 × 10-5
1.67 × 10-10
1.67 × 104
5.99 × 10-19
1.00 × 10-7
Selected Answer:
1.67 × 10-10
A 0.15 M aqueous solution of the weak acid HA at 25.0 °C has a pH of 5.35. The value of Ka for HA is ________.
Answers:
3.0 × 10-5
1.8 × 10-5
7.1 × 10-9
1.3 × 10-10
3.3 × 104
Selected Answer:
1.3 × 10-10
Classify the following compounds as weak acids (W) or strong acids (S):
hydrocyanic acid hydrofluoric acid phenol
Answers:
W W W
S S S
S W W
W S S
W S W
Selected Answer:
W W W
Of the compounds below, a 0.1 M aqueous solution of ________ will have the highest pH.
Answers:
KCN, Ka of HCN = 4.0 × 10-10
NH4NO3, Kb of NH3 = 1.8 × 10-5
NaOAc, Ka of HOAc = 1.8 × 10-5
NaClO, Ka of HClO = 3.2 × 10-8
NaHS, Kb of HS- = 1.8 × 10-7
Selected Answer:
KCN, Ka of HCN = 4.0 × 10-1
Calculate the pH of a solution at 25.0 °C that contains 1.94 × 10-10 M hydronium ions.
Answers:
1.94
4.29
7.00
14.0
Selected Answer:
-log(1.94 x 10-10M = 9.71
Classify the following compounds as weak acids (W) or strong acids (S):
hypochlorous acid perchloric acid chloric acid
Answers:
W S S
S S S
S W W
W W W
W S W
Selected Answer:
W S S
Which of the following aqueous solutions has the lowest [OH-]?
Answers:
a solution with a pH of 3.0
a 1 × 10-4 M solution of HNO3
a solution with a pOH of 12.0
pure water
a 1 × 10-3 M solution of NH4Cl
Selected Answer:
a solution with a pOH of 12.0
What is the conjugate acid of CO32- ?
Answers:
CO22-
HCO22-
H2CO3
HCO3-
none of the above
Selected Answer:
HCO3-
Determine the pOH of a 0.10 M aqueous solution of KF. For hydrofluoric acid, Ka = 7.0 × 10-4.
Answers:
1.00
5.92
8.08
5.01
1.58
Selected Answer:
5.92
Classify the following compounds as weak acids (W) or strong acids (S):
nitrous acid hydrochloric acid hydrofluoric acid
Answers:
W W W
S S S
S W W
W S S
W S W
Selected Answer:
W S W
The Ka of hypochlorous acid (HClO) is 3.0 × 10-8 at 25.0 °C. Calculate the pH of a 0.0385 M hypochlorous acid solution.
Answers:
3.05
9.53
4.47
6.52
-3.05
Selected Answer:
4.47
The pH of a 0.30 M solution of a weak acid is 2.67. What is the Ka for this acid?
Answers:
2.1 × 10-4
4.4 × 10-4
1.5 × 10-4
6.6 × 10-4
none of the above
Selected Answer:
none of the above
Calculate the pOH of a solution at 25.0 °C that contains 1.94 × 10-10 M hydronium ions.
Answers:
1.94
4.29
7.00
14.0
9.71
Selected Answer:
4.29
Calculate the pOH of a 0.0727 M aqueous sodium cyanide solution at
25.0 °C. Kb for CN- is
4.9 × 10-10.
Answers:
9.33
10.00
5.22
1.14
8.78
Selected Answer:
5.22
The Ka of hypochlorous acid (HClO) is 3.0 × 10-8 at 25.0 °C. Calculate the pH of a 0.0385 M hypochlorous acid solution.
Answers:
3.05
9.53
4.47
6.52
-3.05
Selected Answer:
4.47
The conjugate acid of CH3NH2 is ________.
Answers:
CH3NH2
CH3NH3+
CH3NH2+
CH3NH+
Selected Answer:
CH3NH3+
A 0.0035 M aqueous solution of a particular compound has pH = 2.46. The compound is ________.
Answers:
a weak base
a weak acid
a strong acid
a strong base
a salt
Selected Answer:
a strong acid
Calculate the concentration (in M) of hydroxide ions in a solution at 25.0 °C with a pOH of 4.223.
Answers:
5.98 × 10-5
1.67 × 10-10
1.67 × 104
5.99 × 10-19
1.00 × 10-7
Selected Answer:
5.98 × 10-5
What is the pH of an aqueous solution at 25.0 °C that contains 3.98 × 10-9 M hydronium ion?
Answers:
8.400
5.600
9.000
3.980
7.000
Selected Answer:
8.400
Which of the following aqueous solutions has the highest [OH-]?
Answers:
a solution with a pH of 3.0
a 1 × 10-4 M solution of HNO3
a solution with a pOH of 12.0
pure water
a 1 × 10-3 M solution of NH4Cl
Selected Answer:
pure water
A Br∅nsted-Lowry base is defined as a substance that ________.
Answers:
increases [H+] when placed in H2O
decreases [H+] when placed in H2O
increases [OH-] when placed in H2O
acts as a proton acceptor
acts as a proton donor
Selected Answer:
acts as a proton acceptor
An aqueous solution of ________ will produce a neutral solution.
Answers:
LiNO3
NaNO2
KF
Rb2CO3
NH4NO3
Selected Answer:
LiNO3
A 0.0035 M aqueous solution of a particular compound has pH = 2.46. The compound is ________.
Answers:
a weak base
a weak acid
a strong acid
a strong base
a salt
Selected Answer:
a strong acid
Determine the pH of a 0.35 M aqueous solution of CH3NH2 (methylamine). The Kb of methylamine is 4.4 × 10-4.
Answers:
10.00
3.86
12.09
1.96
13.24
Selected Answer:
12.09
Calculate the molarity of hydroxide ion in an aqueous solution that has a pOH of 3.00.
Answers:
1.0 × 10-3
11.00
1.0 × 10-11
3.0 × 10-14
1.1 × 10-13
Selected Answer:
1.0 × 10-3
What is the pH of an aqueous solution at 25.0 °C that contains 3.98 × 10-9 M hydroxide ion?
Answers:
8.40
5.60
9.00
3.98
7.00
Selected Answer:
5.60
What is the conjugate acid of NH3?
Answers:
NH3
NH2+
NH3+
NH4+
NH4OH
Selected Answer:
NH4+