front 1 MeOH -----> H+ | back 1 Glycoside formation. Turns all substituents into OMe but the CH2OH |
front 2 CH3-I ------> Ag2O | back 2 Methylation. Turn all substituents into OMe including the CH2OH. |
front 3 H2O-----> H+ | back 3 Hydrolysis. Turns the anomeric substituent into an OH and leaves a floating H+ in solution. |
front 4 HNO3 | back 4 Reduces/Oxidizes. Turns the top and bottommost carbons into CO2H |
front 5 An optically inactive molecule is ________ | back 5 Symmetrical or has a plane of symmetry |
front 6 An optically active molecule is ________ | back 6 Not symmetrical. Does not have a line of symmetry. |
front 7 NaBH4 | back 7 Turns the top and bottom ends of the structure into OH |
front 8 (1) HCN (2)Pd/H2 (3) H3O+ | back 8 Adds an OH in both the D and L configuration. Results in 2 epimers. Kiliani Fischer Reaction |
front 9 (1) H2NOH (2) Ar2O ArONa (3) NaOMe MeOH | back 9 Wohl's Degradation. An OH is removed from the structure. |
front 10 LiAlH4 | back 10 Gets rid of the C=O group in the structure, but leaves everything else the same |
front 11 (1) NaBH4 or NaBH3CN or H2/Ni | back 11 Combines 2 structures at a Nitrogen and gets rid of an H2O (A =O and 2Hs) |
front 12 NH3 and then NaBH4 | back 12 Adds the NH3 to the alpha carbon to become NH4 and then H2O leaves. |