front 1 the potential of an electrode depends on the concentrations of one or more | back 1 species present in the solution in which the electrode is immersed |
front 2 the potential, E, of the glass electrode depends on the | back 2 hydronium ion concentrations |
front 3 Combination electrodes are available which combine the functions of the | back 3 calomel reference electrode, the internal reference in the glass electrode, and the concentration of H3O^+ in the analyte solution change |
front 4 the initial pH of a water solution of sodium carbonate is about | back 4 10.5 due to hydrolysis of the CO3^2- ion |
front 5 The continued addition of HCl titrant results in | back 5 a more rapid drop in pH to slightly above 7 |
front 6 The first inflection point in the curve corresponds to first | back 6 equivalence point at about pH 8 |
front 7 The second equivalence point occurs in | back 7 in pH 4 |
front 8 The endpoints for the first and second equivalence point volumes are | back 8 determined graphically using the 1st and second derivatives of the titration curve. |
front 9 The reaction for the first equivalence point is: | back 9 CO3^2- (aq)+H2O (l) ---> HCO3^- (aq)+OH^- (aq) |
front 10 for the second equivalence point reaction: | back 10 HCO3^- (aq)+ H3O^+ (aq) --->H2CO3 (aq) +H2O (l) |