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Chapter 4 - Alkanes

front 1

Give the IUPAC name for the following compound

back 1

1-sec-butyl-4-isopropyl-2-methylcyclohexane

front 2

Give the IUPAC name for the following compound

back 2

3,5-diethyl-2-methylheptane

front 3

Give the IUPAC name for the following compound

back 3

1-cyclopentylhexane

front 4

Draw an appropriate structure given the IUPAC name of the following compound:

5-sec-butyl-3-ethyl-2,7-dimethyldecane

back 4

front 5

Draw an appropriate structure given the IUPAC name of the following compound:

4-ethyl-3,6-dimethyloctane

back 5

front 6

Convert the following structure to a Newman Projection. Rotate projection 60 degrees and identify which conformation is more stable.

back 6

**The rotated conformation is neither the most or least stable. The least stable would have the methyl groups eclipsing each other.

front 7

Convert the following structure to a Newman Projection (The eye is on the lefthand side). Rotate projection 60 degrees and identify which conformation is higher in energy.

back 7

front 8

Classify the following reaction as oxidation, reduction, or neither.

back 8

Neither

front 9

Classify the following reaction as oxidation, reduction, or neither.

back 9

Oxidation

front 10

Draw another conformer of the structure provided of cis-cyclohexane-1,3-diol. Identify which is most stable.

back 10

The conformer following the ring flip is more stable because the substituents (large groups) are avoiding 1,3-trans-diaxial interactions.

front 11

Draw an appropriate conformer for cis-1-ethyl-3-isopropylcyclohexane. Perform a ring flip, and then determine which is the least stable conformation.

back 11

front 12

Draw a possible chair conformation for the substituted cyclohexane

back 12

front 13

Draw a possible chair conformation for the substituted cyclohexane

back 13