front 1 From the restrictions on the three quantum numbers that define an orbital, which set of three quantum numbers listed below is forbidden? a. n = 3, l = 2, m l = −2 b. n = 3, l = 1, m l = +1 c. n = 3, l = 3, m l = 3 d. n = 3, l = 0, m l = 0 e. n = 3, l = 2, m l = +2 | back 1 Answer: c. n = 3, l = 3, m l = 3 |
front 2 Of the following, ________ radiation has the shortest wavelength: X-ray radio microwave ultraviolet infrared | back 2 Answer: X-rayAnswers |
front 3 m l is known as the: a. magnetic quantum number, and it specifies the orbital orientation b. angular momentum quantum number, and it specifies the orbital shape c. principal quantum number, and it specifies the average distance from the nucleus d. angular momentum quantum number, and it specifies the orbital orientation e. magnetic quantum number, and it specifies the average distance from the nucleus | back 3 Answers: a. magnetic quantum number, and it specifies the orbital orientation |
front 4 The lowest energy shell that contains f orbitals is the shell with n = ________. 3 2 4 1 5 | back 4 Answer: 4 |
front 5 Which one of the following is an incorrect orbital notation? 2s 3py 3f 4dxy 4s | back 5 Answer: 3f |
front 6 The wavelength of light that has a frequency of 1.20 x 1013 s-1 is ________ m. 25.0 2.50 x 10-5 0.0400 12.0 2.5 | back 6 Answer: 2.50 x 10-5 |
front 7 The n = 1 shell contains ________ p orbitals. All the other shells contain ________ p orbitals. 3, 6 0, 3 6, 2 3, 3 0, 6 | back 7 Answer: 0, 3 |
front 8 What is the frequency (s−1) of electromagnetic radiation that has a wavelength of 5.2 m? a. 0.19 s−1 b. s−1 c. s−1 d. s−1 e. s−1 | back 8 Answer: d. s−1 |
front 9 When the electron in a hydrogen atom moves from n = 8 to n = 2 light with a wavelength of ________ nm is emitted. 657 93.8 411 487 389 | back 9 Answer: 389 |
front 10 The energy of a photon that has a wavelength of 8.33 x 10-6 m is ________ J. 2.20 x 10-26 3.60 x 1013 2.39 x 10-20 2.7 x 109 4.5 x 10-25 | back 10 Answer: 2.39 x 10-20 |
front 11 The n = 8 to n = 4 transition in the Bohr hydrogen atom occurs in the ________ region of the electromagnetic spectrum. infrared visible ultraviolet microwave X-ray | back 11 Answers: infrared |
front 12 What is the de Broglie wavelength (m) of a 25-g object moving at a speed of 5.0 m/s? 1.9 x 1032 m 5.3 x 10-33 m 6.6 x 10-36 m 3.32 x 10-36 m 3.02 x 1045 m | back 12 Answer: 5.3 x 10-33 m |
front 13 he energy of a photon that has a wavelength of 9.0 m is ________ J. 2.2 x 10-26 4.5 x 1025 6.0 x 10-23 2.7 x 109 4.5 x 10-25 | back 13 Answer: 2.2 x 10-26 |
front 14 The complete electron configuration of sulfur, element 16, is ________. 1s22s22p63s23p4 1s22s22p103s2 1s42s42p63s2 1s42s42p8 1s62s62p23s2 | back 14 Answer: 1s22s22p63s23p4 |
front 15 A local AM radio station broadcasts at a wavelength of 349 m. Calculate the energy of the wavelength at which it is broadcasting. a. 6.33 × 10-45 J b. 6.93 × 10-39 J c. 5.69 × 10-28 J d. 7.71 × 10-40 J e. 8.59 × 105 J | back 15 Answer: c. 5.69 × 10-28 J |
front 16 The wavelength of light that has a frequency of 1.20 x 1013 s-1 is ________ m. 25.0 2.50 x 10-5 0.0400 12.0 2.5 | back 16 Answer: 2.50 x 10-5 |
front 17 The principal quantum number for the outermost electrons in a Te atom in the ground state is ________. 3 4 5 7 6 | back 17 Answer: 5 |
front 18 Which one of the following is considered to be ionizing radiation? visible light radio waves X-rays microwaves infrared radiation | back 18 Answer: X-rays |
front 19 How many electrons can be described by the quantum numbers n = 3, l = 3, m l = −2? a. 2 b. 14 c. 10 d. 7 e. 0 | back 19 Answers: e. 0 |
front 20 The energy of a photon that has a frequency of 8.21 x 1015 s-1 is ________ J. 8.08 x 10-50 1.99 x 10-25 5.44 x 10-18 1.24 x 1049 1.26 x 10-19 | back 20 Answer: 5.44 x 10-18 |
front 21 The energy of a photon that has a frequency of 1.821 x 1016 s-1 is ________ J. 5.44 x 10-18 1.99 x 10-25 3.49 x 10-48 1.21 x 10-17 5.46 x 10-24 | back 21 Answer: 1.21 x 10-17 |
front 22 A spectrum containing only specific wavelengths is called a(n) ________ spectrum. line continuous visible Rydberg invariant | back 22 Answer: line |
front 23 The wavelength of light that has a frequency of 1.20 x 1013 s-1 is ________ m. 25.0 2.50 x 10-5 0.0400 12.0 2.5 | back 23 Answer: 2.50 x 10-5 |
front 24 There are ________ unpaired electrons in a ground state fluorine atom 0 1 2 3 4 | back 24 Answer: 1 |
front 25 Which one of the following represents an acceptable set of quantum numbers for an electron in an atom? (arranged as n, l, ml, and ms) 3, 0, 0, -1/2 3, -1, -4, 1/2 3, -3, 1, -1/2 0, 2, 1, 0 3, 3, 4, 3 | back 25 Answer: 3, 0, 0, -1/2 |
front 26 Which two elements have the same ground-state electron configuration? Pd and Pt Cu and Ag Fe and Cu Cl and Ar No two elements have the same ground-state electron configuration. | back 26 Answer: No two elements have the same ground-state electron configuration. |
front 27 How many electrons can be described by the quantum numbers n = 4, l = 1?a. 2 b. 6 c. 0 d. 18 e. 3 | back 27 Answer: b.6 |
front 28 here are ________ unpaired electrons in a ground state chlorine atom. 4 3 2 10 | back 28 Answer: 1 |
front 29 The frequency of a photon that has an energy of 8.5 x 10-12 J is ________ s-1. 1.3 x 1022 1.8 x 10-16 2.5 x 10-15 5.4 x 10-8 2.5 x 1015 | back 29 Answer: 1.3 x 1022 |
front 30 The angular momentum quantum number is 3 in ________ orbitals. s p d f a | back 30 Answer: f |
front 31 [Ne]3s23p3 is the electron configuration of a(n) ________ atom. As V P Sb Sn | back 31 Answer: P |
front 32 What type of orbital is designated by n = 5, l = 2, m l = +1? a. 2s b. 5d c. 2f d. 5f
| back 32 Answer: b. 5d |
front 33 All of the orbitals in a given electron shell have the same value as the ________ quantum number. principal angular momentum magnetic spin psi | back 33 Answer: principal |
front 34 The frequency of a photon that has an energy of 3.7 x 10-18 J is ________ s-1. 5.6 x 1015 1.8 x 10-16 2.5 x 10-15 5.4 x 10-8 2.5 x 1015 | back 34 Answer: 5.6 x 1015 |
front 35 How many electrons in an atom can have the quantum numbers n = 3, l = 2?a. 18 b. 6 c. 2 d. 5 e. 10 | back 35 Answer: e. 10 |
front 36 Which one of the following orbitals can hold two electrons? 2px 3s 4dxy all of the above none of the above | back 36 Answer: all of the above |
front 37 How many electrons can be described by the quantum numbers n = 3, l = 2, m l = −2? a. 10 b. 6 c. 0 d. 2 e. 14 | back 37 Answer: d. 2 |
front 38 The ________ quantum number defines the shape of an orbital. spin magnetic principal angular momentum psi | back 38 Answer: angular momentum |
front 39 There are ________ unpaired electrons in a ground state chlorine atom. 4 3 2 1 0 | back 39 Answer: 1 |
front 40 Calculate the de Broglie wavelength of an alpha particle (mass = 6.64 x 10-27 kg) moving at a speed of 1.52 x 107 m/s. a. 5.08 x 105 m b. 8.68 x 10-59 m c. 6.57 x 10-15 m d. 1.97 x 10-6 m e. 4.55 x 108 m | back 40 Answer: c. 6.57 x 10-15 m |
front 41 The energy of a photon that has a wavelength of 13.2 nm is ________ J. 9.55 x 10-25 1.62 x 10-17 1.99 x 10-25 4.42 x 10-23 1.51 x 10-17 | back 41 Answer: 1.51 x 10-17 |
front 42 Calculate the energy for the transition of an electron from the n = 4 level to the n = 1 level of a hydrogen atom. a. −2.178 × 10-18 J b. −1.361 × 10-19 J c. −2.042 × 10-18 J d. −5.445 × 10-19 J e. −3.165 × 10-19 J | back 42 Answer: c. −2.042 × 10-18 J |
front 43 According to the Heisenberg Uncertainty Principle, it is impossible to know precisely both the position and the ________ of an electron. mass color momentum shape charge | back 43 Answer: momentum |
front 44 The lowest energy shell that contains f orbitals is the shell with n = ________. 3 2 4 1 5 | back 44 Answer: 4 |
front 45 Which one of the following is not a valid value for the magnetic quantum number of an electron in a 5d subshell? 2 3 0 1 -1 | back 45 Answer: 3 |
front 46 The 3p subshell in the ground state of atomic xenon contains ________ electrons. 2 6 8 10 36 | back 46 Answer: 6 |
front 47 What is the frequency (s-1) of a photon that has an energy of 4.38 x 10-18 J? 436 s-1 6.61 x 1015 s-1 1.45 x 10-16 s-1 2.30 x 107 s-1 1.31 x 10-9 s-1 | back 47 Answer: 6.61 x 1015 s-1 |
front 48 In Bohr's atomic theory, when an electron moves from one energy level to another energy level more distant from the nucleus: a. Energy is emitted. b. Energy is absorbed. c. No change in energy occurs. d. Light is emitted. e. none of these. | back 48 Answer: b. Energy is absorbed |
front 49 What is the wavelength of light (nm) that has a frequency 4.62 x 1014 s-1? 932 nm 649 nm 1.39 x 1023 nm 1.54 x 10-3 nm 1.07 x 106 nm | back 49 Answer: 649 nm |
front 50 Which one of the following is an incorrect orbital notation? 2s 3py 3f 4dxy 4s | back 50 Answer: 3f |
front 51 From the restrictions on the three quantum numbers that define an orbital, which set of three quantum numbers listed below is forbidden? a. n = 3, l = 2, m l = −2 b. n = 3, l = 3, m l = 3 c. n = 3, l = 1, m l = +1 d. n = 3, l = 0, m l = 0 e. n = 3, l = 2, m l = +2 | back 51 Answer: b. n = 3, l = 3, m l = 3 |
front 52 How many sublevels are contained in the second energy level (n = 2) of a given atom? a. 2 b. 4 c. 3 d. 1 e. 0 | back 52 Answer: a. 2 |
front 53 An electron cannot have the quantum numbers n = ________, l = ________, ml = ________. 6, 1, 0 3, 2, 3 3, 2, -2 1, 0, 0 3, 2, 1 | back 53 Answer: 3, 2, 3 |
front 54 Place the following types of electromagnetic radiation in order of decreasing energy: Ultraviolet radio waves microwaves a. Ultraviolet > radio waves > microwaves b. Microwaves > radio waves > ultraviolet c. Radio waves > microwaves > ultraviolet d. Radio waves > ultraviolet > microwaves e. Ultraviolet > microwaves > radio waves | back 54 e. Ultraviolet > microwaves > radio waves |
front 55 When n = 4, how many d orbitals are present ? a. 10 b. 18 c. 5 d. 7 e. 2 | back 55 Answer: c. 5 |
front 56 There are ________ unpaired electrons in a ground state chlorine atom. 4 3 2 1 0 | back 56 Answer: 1 |
front 57 Calculate the energy for the transition of an electron from the n = 4 level to the n = 1 level of a hydrogen atom. a. −2.042 × 10-18 J b. −3.165 × 10-19 J c. −2.178 × 10-18 J d. −1.361 × 10-19 J e. −5.445 × 10-19 J | back 57 Answer: a. −2.042 × 10-18 J |
front 58 The uncertainty principle states that ________. matter and energy are really the same thing it is impossible to know anything with certainty it is impossible to know the exact position and momentum of an electron there can only be one uncertain digit in a reported number it is impossible to know how many electrons there are in an atom | back 58 Answer: it is impossible to know the exact position and momentum of an electron |
front 59 Which quantum numbers must be the same for the orbitals that they designate to be degenerate in a many-electron system? n, l, and ml n only n, l, ml, and ms ms only n and l only | back 59 Answer: n and l only |
front 60 What is the frequency of light (s-1) that has a wavelength of 3.12 x 10-3 cm? 3.69 s-1 2.44 x 1016 s-1 9.62 x 1012 s-1 4.10 x 10-17 s-1 1.04 x 10-13 s-1 | back 60 Answer: 9.62 x 1012 s-1 |
front 61 The energy of a photon that has a frequency of 8.21 x 1015 s-1 is ________ J. 8.08 x 10-50 1.99 x 10-25 5.44 x 10-18 1.24 x 1049 1.26 x 10-19 | back 61 Answer: 5.44 x 10-18 |
front 62 In a px orbital, the subscript x denotes the ________. energy of the electron spin of the electrons probability of the shell size of the orbital axis along which the orbital is aligned | back 62 Answer: axis along which the orbital is aligned |
front 63 Of the following transitions in the Bohr hydrogen atom, the ________ transition results in the absorption of the highest-energy photon. n = 2 → n = 5 n = 4 → n = 2 n = 3 → n = 2 n = 5 → n = 2 All transitions absorb photons of equivalent energy. | back 63 Answers: n = 2 → n = 5 |
front 64 There are ________ orbitals in the second shell. 1 2 4 8 9 | back 64 Answer: 4 |
front 65 How many f orbitals have the value n = 2? a. 1 b. 5 c. 3 d. 7 e. 0 | back 65 Answer: e. 0 |
front 66 What is the wavelength of a photon that has an energy of J? ( c = 2.998 × 10 8 m/s, h = 6.626 × 10 -34 J·s) a. 1.31912x10-1 nm b. 6.6405070933X1034nm c. 451 nm d. 8.74048912x10-36 nm | back 66 Answer: c. 451 nm |
front 67 Of the following transitions in the Bohr hydrogen atom, the ________ transition results in the emission of the highest-energy photon. n = 6 → n = 4 n = 2 → n = 7 n = 4 → n = 6 n = 1 → n = 4 All transitions emit photons of equivalent energy. | back 67 Answer: n = 6 → n = 4 |
front 68 How many quantum numbers are necessary to designate a particular electron in an atom? 3 4 2 1 5 | back 68 Answer: 4 |
front 69 How many different values of ml are possible in the 4f sublevel? a. 3 b. 5 c. 7 d. 1 e. 2 | back 69 Answer: c. 7 |
front 70 Which one of the following is an incorrect subshell notation? 4f 2d 3s 2p 3d | back 70 Answer: 2d |
front 71 The angular momentum quantum number (l) value of 2 indicates the ________ subshell. d f s p 0.5 | back 71 Answer: d |
front 72 The frequency of a photon that has an energy of 3.7 x 10-18 J is ________ s-1. 5.6 x 1015 1.8 x 10-16 2.5 x 10-15 5.4 x 10-8 2.5 x 1015 | back 72 Answer: 5.6 x 1015 |
front 73 The largest principal quantum number in the ground state electron configuration of barium is ________. 1 2 6 4 5 | back 73 Answer: 6 |
front 74 The 4d subshell in the ground state of atomic xenon contains ________ electrons. 2 6 8 10 36 | back 74 Answer: 10 |
front 75 How many electrons can be described by the quantum numbers n = 3, l = 3, m l = −2? e. 2 a. 10 b. 14 c. 0 d. 7 e. 2 | back 75 Answer: c. 0 |
front 76 What is the de Broglie wavelength (m) of a 25-g object moving at a speed of 5.0 m/s? Answers: 1.9 x 1032 m 5.3 x 10-33 m 6.6 x 10-36 m 3.32 x 10-36 m 3.02 x 1045 m | back 76 Selected Answer: 5.3 x 10-33 m |
front 77 The principal quantum number for the outermost electrons in a Te atom in the ground state is ________. 3 4 5 6 7 | back 77 Answer: 5 |
front 78 The elements in the ________ period of the periodic table have a core-electron configuration that is the same as the electron configuration of neon. first second third fourth fifth | back 78 Answer: third |
front 79 Which one of the following represents an acceptable set of quantum numbers for an electron in an atom? (arranged as n, l, ml, and ms) 3, 0, 0, -1/2 3, -1, -4, 1/2 3, -3, 1, -1/2 0, 2, 1, 0 3, 3, 4, 3 | back 79 Answers: 3, 0, 0, -1/2 |
front 80 What is the wavelength of light (nm) that has a frequency of 6.44 x 1013 s-1? 4660 nm 6490 nm 4.66 x 10-8 nm 6.49 x 10-8 nm 932 nm | back 80 Answer: 4660 nm |
front 81 What is the frequency (s−1) of electromagnetic radiation that has a wavelength of 5.2 m? a. 1.3x1034s−1 b. 5.7x107 s−1 c. 0.19 s−1 | back 81 Answer: b. 5.7x107 s−1 |
front 82 How many different principal quantum numbers can be found in the ground-state electron configuration of nickel? 2 3 4 5 6 | back 82 Answer: 4 |
front 83 According to the Heisenberg Uncertainty Principle, it is impossible to know precisely both the position and the ________ of an electron. mass color momentum shape charge | back 83 Answer: momentum |
front 84 How many p-orbitals are occupied in a O atom? 5 6 0 3 1 | back 84 Answer: 3 |
front 85 What is the energy of a photon of electromagnetic radiation with a wavelength of 117.6 nm? ( c = 2.998 × 10 8 m/s, h = 6.626 × 10 -34 J·s) a. 2.5493197279 x10-18 J b. 1.6991792517x10-18J c. 7.792176x10-41 J | back 85 Answer: b.1.6991792517x10-18J |
front 86 The complete electron configuration of sulfur, element 16, is ________. 1s22s22p63s23p4 1s22s22p103s2 1s42s42p63s2 1s42s42p8 1s62s62p23s2 | back 86 Answer: 1s22s22p63s23p4 |
front 87 Which of the following elements has a ground-state electron configuration different from the predicted one? Cu Ca Xe Cl Ti | back 87 Answer: Cu |
front 88 A ________ orbital is degenerate with a 5dz2 in a many-electron atom. 5pz 4dz2 5s 5dxy 4dzz | back 88 Answer: 5dxy |
front 89 How many quantum numbers are necessary to designate a particular electron in an atom? 3 4 2 1 5 | back 89 Answer: 4 |