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Chemistry Chapter 6 Final Exam

front 1

From the restrictions on the three quantum numbers that define an orbital, which set of three quantum numbers listed below is forbidden?

a. n = 3, l = 2, m l = −2

b. n = 3, l = 1, m l = +1

c. n = 3, l = 3, m l = 3

d. n = 3, l = 0, m l = 0

e. n = 3, l = 2, m l = +2

back 1

Answer: c. n = 3, l = 3, m l = 3

front 2

Of the following, ________ radiation has the shortest wavelength:

X-ray

radio

microwave

ultraviolet

infrared

back 2

Answer: X-rayAnswers

front 3

m l is known as the:

a. magnetic quantum number, and it specifies the orbital orientation

b. angular momentum quantum number, and it specifies the orbital shape

c. principal quantum number, and it specifies the average distance from the nucleus

d. angular momentum quantum number, and it specifies the orbital orientation

e. magnetic quantum number, and it specifies the average distance from the nucleus

back 3

Answers: a. magnetic quantum number, and it specifies the orbital orientation

front 4

The lowest energy shell that contains f orbitals is the shell with n = ________.

3

2

4

1

5

back 4

Answer: 4

front 5

Which one of the following is an incorrect orbital notation?

2s

3py

3f

4dxy

4s

back 5

Answer: 3f

front 6

The wavelength of light that has a frequency of 1.20 x 1013 s-1 is ________ m.

25.0

2.50 x 10-5

0.0400

12.0

2.5

back 6

Answer:

2.50 x 10-5

front 7

The n = 1 shell contains ________ p orbitals. All the other shells contain ________ p orbitals.

3, 6

0, 3

6, 2

3, 3

0, 6

back 7

Answer: 0, 3

front 8

What is the frequency (s−1) of electromagnetic radiation that has a wavelength of 5.2 m?

a. 0.19 s−1

b. s−1

c. s−1

d. s−1

e. s−1

back 8

Answer: d. s−1

front 9

When the electron in a hydrogen atom moves from n = 8 to n = 2 light with a wavelength of ________ nm is emitted.

657

93.8

411

487

389

back 9

Answer: 389

front 10

The energy of a photon that has a wavelength of 8.33 x 10-6 m is ________ J.

2.20 x 10-26

3.60 x 1013

2.39 x 10-20

2.7 x 109

4.5 x 10-25

back 10

Answer:

2.39 x 10-20

front 11

The n = 8 to n = 4 transition in the Bohr hydrogen atom occurs in the ________ region of the electromagnetic spectrum.

infrared

visible

ultraviolet

microwave

X-ray

back 11

Answers: infrared

front 12

What is the de Broglie wavelength (m) of a 25-g object moving at a speed of 5.0 m/s?

1.9 x 1032 m

5.3 x 10-33 m

6.6 x 10-36 m

3.32 x 10-36 m

3.02 x 1045 m

back 12

Answer:

5.3 x 10-33 m

front 13

he energy of a photon that has a wavelength of 9.0 m is ________ J.

2.2 x 10-26

4.5 x 1025

6.0 x 10-23

2.7 x 109

4.5 x 10-25

back 13

Answer:

2.2 x 10-26

front 14

The complete electron configuration of sulfur, element 16, is ________.

1s22s22p63s23p4

1s22s22p103s2

1s42s42p63s2

1s42s42p8

1s62s62p23s2

back 14

Answer:

1s22s22p63s23p4

front 15

A local AM radio station broadcasts at a wavelength of 349 m. Calculate the energy of the wavelength at which it is broadcasting.

a. 6.33 × 10-45 J

b. 6.93 × 10-39 J

c. 5.69 × 10-28 J

d. 7.71 × 10-40 J

e. 8.59 × 105 J

back 15

Answer: c. 5.69 × 10-28 J

front 16

The wavelength of light that has a frequency of 1.20 x 1013 s-1 is ________ m.

25.0

2.50 x 10-5

0.0400

12.0

2.5

back 16

Answer:

2.50 x 10-5

front 17

The principal quantum number for the outermost electrons in a Te atom in the ground state is ________.

3

4

5

7

6

back 17

Answer: 5

front 18

Which one of the following is considered to be ionizing radiation?

visible light

radio waves

X-rays

microwaves

infrared radiation

back 18

Answer: X-rays

front 19

How many electrons can be described by the quantum numbers n = 3, l = 3, m l = −2?

a. 2

b. 14

c. 10

d. 7

e. 0

back 19

Answers: e. 0

front 20

The energy of a photon that has a frequency of 8.21 x 1015 s-1 is ________ J.

8.08 x 10-50

1.99 x 10-25

5.44 x 10-18

1.24 x 1049

1.26 x 10-19

back 20

Answer:

5.44 x 10-18

front 21

The energy of a photon that has a frequency of 1.821 x 1016 s-1 is ________ J.

5.44 x 10-18

1.99 x 10-25

3.49 x 10-48

1.21 x 10-17

5.46 x 10-24

back 21

Answer:

1.21 x 10-17

front 22

A spectrum containing only specific wavelengths is called a(n) ________ spectrum.

line

continuous

visible

Rydberg

invariant

back 22

Answer: line

front 23

The wavelength of light that has a frequency of 1.20 x 1013 s-1 is ________ m.

25.0

2.50 x 10-5

0.0400

12.0

2.5

back 23

Answer:

2.50 x 10-5

front 24

There are ________ unpaired electrons in a ground state fluorine atom

0

1

2

3

4

back 24

Answer: 1

front 25

Which one of the following represents an acceptable set of quantum numbers for an electron in an atom? (arranged as n, l, ml, and ms)

3, 0, 0, -1/2

3, -1, -4, 1/2

3, -3, 1, -1/2

0, 2, 1, 0

3, 3, 4, 3

back 25

Answer:

3, 0, 0, -1/2

front 26

Which two elements have the same ground-state electron configuration?

Pd and Pt

Cu and Ag

Fe and Cu

Cl and Ar

No two elements have the same ground-state electron configuration.

back 26

Answer: No two elements have the same ground-state electron configuration.

front 27

How many electrons can be described by the quantum numbers n = 4, l = 1?a. 2

b. 6

c. 0

d. 18

e. 3

back 27

Answer:

b.6

front 28

here are ________ unpaired electrons in a ground state chlorine atom.

4

3

2

10

back 28

Answer: 1

front 29

The frequency of a photon that has an energy of 8.5 x 10-12 J is ________ s-1.

1.3 x 1022

1.8 x 10-16

2.5 x 10-15

5.4 x 10-8

2.5 x 1015

back 29

Answer:

1.3 x 1022

front 30

The angular momentum quantum number is 3 in ________ orbitals.

s

p

d

f

a

back 30

Answer: f

front 31

[Ne]3s23p3 is the electron configuration of a(n) ________ atom.

As

V

P

Sb

Sn

back 31

Answer:

P

front 32

What type of orbital is designated by n = 5, l = 2, m l = +1?

a. 2s

b. 5d

c. 2f

d. 5f
e. 5p

back 32

Answer:

b. 5d

front 33

All of the orbitals in a given electron shell have the same value as the ________ quantum number.

principal

angular

momentum

magnetic

spin

psi

back 33

Answer: principal

front 34

The frequency of a photon that has an energy of 3.7 x 10-18 J is ________ s-1.

5.6 x 1015

1.8 x 10-16

2.5 x 10-15

5.4 x 10-8

2.5 x 1015

back 34

Answer:

5.6 x 1015

front 35

How many electrons in an atom can have the quantum numbers n = 3, l = 2?a. 18

b. 6

c. 2

d. 5

e. 10

back 35

Answer: e. 10

front 36

Which one of the following orbitals can hold two electrons?

2px

3s

4dxy

all of the above

none of the above

back 36

Answer:

all of the above

front 37

How many electrons can be described by the quantum numbers n = 3, l = 2, m l = −2?

a. 10

b. 6

c. 0

d. 2

e. 14

back 37

Answer:

d. 2

front 38

The ________ quantum number defines the shape of an orbital.

spin

magnetic

principal

angular momentum

psi

back 38

Answer: angular momentum

front 39

There are ________ unpaired electrons in a ground state chlorine atom.

4

3

2

1

0

back 39

Answer: 1

front 40

Calculate the de Broglie wavelength of an alpha particle (mass = 6.64 x 10-27 kg) moving at a speed of 1.52 x 107 m/s.

a. 5.08 x 105 m

b. 8.68 x 10-59 m

c. 6.57 x 10-15 m

d. 1.97 x 10-6 m

e. 4.55 x 108 m

back 40

Answer:

c. 6.57 x 10-15 m

front 41

The energy of a photon that has a wavelength of 13.2 nm is ________ J.

9.55 x 10-25

1.62 x 10-17

1.99 x 10-25

4.42 x 10-23

1.51 x 10-17

back 41

Answer:

1.51 x 10-17

front 42

Calculate the energy for the transition of an electron from the n = 4 level to the n = 1 level of a hydrogen atom.

a. −2.178 × 10-18 J

b. −1.361 × 10-19 J

c. −2.042 × 10-18 J

d. −5.445 × 10-19 J

e. −3.165 × 10-19 J

back 42

Answer:

c. −2.042 × 10-18 J

front 43

According to the Heisenberg Uncertainty Principle, it is impossible to know precisely both the position and the ________ of an electron.

mass

color

momentum

shape

charge

back 43

Answer: momentum

front 44

The lowest energy shell that contains f orbitals is the shell with n = ________.

3

2

4

1

5

back 44

Answer: 4

front 45

Which one of the following is not a valid value for the magnetic quantum number of an electron in a 5d subshell?

2

3

0

1

-1

back 45

Answer: 3

front 46

The 3p subshell in the ground state of atomic xenon contains ________ electrons.

2

6

8

10

36

back 46

Answer: 6

front 47

What is the frequency (s-1) of a photon that has an energy of 4.38 x 10-18 J?

436 s-1

6.61 x 1015 s-1

1.45 x 10-16 s-1

2.30 x 107 s-1

1.31 x 10-9 s-1

back 47

Answer:

6.61 x 1015 s-1

front 48

In Bohr's atomic theory, when an electron moves from one energy level to another energy level more distant from the nucleus:

a. Energy is emitted.

b. Energy is absorbed.

c. No change in energy occurs.

d. Light is emitted.

e. none of these.

back 48

Answer:

b. Energy is absorbed

front 49

What is the wavelength of light (nm) that has a frequency 4.62 x 1014 s-1?

932 nm

649 nm

1.39 x 1023 nm

1.54 x 10-3 nm

1.07 x 106 nm

back 49

Answer:

649 nm

front 50

Which one of the following is an incorrect orbital notation?

2s

3py

3f

4dxy

4s

back 50

Answer:

3f

front 51

From the restrictions on the three quantum numbers that define an orbital, which set of three quantum numbers listed below is forbidden?

a. n = 3, l = 2, m l = −2

b. n = 3, l = 3, m l = 3

c. n = 3, l = 1, m l = +1

d. n = 3, l = 0, m l = 0

e. n = 3, l = 2, m l = +2

back 51

Answer:

b. n = 3, l = 3, m l = 3

front 52

How many sublevels are contained in the second energy level (n = 2) of a given atom?

a. 2

b. 4

c. 3

d. 1

e. 0

back 52

Answer:

a. 2

front 53

An electron cannot have the quantum numbers n = ________, l = ________, ml = ________.

6, 1, 0

3, 2, 3

3, 2, -2

1, 0, 0

3, 2, 1

back 53

Answer:

3, 2, 3

front 54

Place the following types of electromagnetic radiation in order of decreasing energy:

Ultraviolet radio waves microwaves

a. Ultraviolet > radio waves > microwaves

b. Microwaves > radio waves > ultraviolet

c. Radio waves > microwaves > ultraviolet

d. Radio waves > ultraviolet > microwaves

e. Ultraviolet > microwaves > radio waves

back 54

e. Ultraviolet > microwaves > radio waves

front 55

When n = 4, how many d orbitals are present ?

a. 10

b. 18

c. 5

d. 7

e. 2

back 55

Answer:

c. 5

front 56

There are ________ unpaired electrons in a ground state chlorine atom.

4

3

2

1

0

back 56

Answer: 1

front 57

Calculate the energy for the transition of an electron from the n = 4 level to the n = 1 level of a hydrogen atom.

a. −2.042 × 10-18 J

b. −3.165 × 10-19 J

c. −2.178 × 10-18 J

d. −1.361 × 10-19 J

e. −5.445 × 10-19 J

back 57

Answer:

a. −2.042 × 10-18 J

front 58

The uncertainty principle states that ________.

matter and energy are really the same thing

it is impossible to know anything with certainty

it is impossible to know the exact position and momentum of an electron

there can only be one uncertain digit in a reported number

it is impossible to know how many electrons there are in an atom

back 58

Answer: it is impossible to know the exact position and momentum of an electron

front 59

Which quantum numbers must be the same for the orbitals that they designate to be degenerate in a many-electron system?

n, l, and ml

n only

n, l, ml, and ms

ms only

n and l only

back 59

Answer: n and l only

front 60

What is the frequency of light (s-1) that has a wavelength of 3.12 x 10-3 cm?

3.69 s-1

2.44 x 1016 s-1

9.62 x 1012 s-1

4.10 x 10-17 s-1

1.04 x 10-13 s-1

back 60

Answer:

9.62 x 1012 s-1

front 61

The energy of a photon that has a frequency of 8.21 x 1015 s-1 is ________ J.

8.08 x 10-50

1.99 x 10-25

5.44 x 10-18

1.24 x 1049

1.26 x 10-19

back 61

Answer:

5.44 x 10-18

front 62

In a px orbital, the subscript x denotes the ________.

energy of the electron

spin of the electrons

probability of the shell

size of the orbital

axis along which the orbital is aligned

back 62

Answer:

axis along which the orbital is aligned

front 63

Of the following transitions in the Bohr hydrogen atom, the ________ transition results in the absorption of the highest-energy photon.

n = 2 → n = 5

n = 4 → n = 2

n = 3 → n = 2

n = 5 → n = 2

All transitions absorb photons of equivalent energy.

back 63

Answers:

n = 2 → n = 5

front 64

There are ________ orbitals in the second shell.

1

2

4

8

9

back 64

Answer: 4

front 65

How many f orbitals have the value n = 2?

a. 1

b. 5

c. 3

d. 7

e. 0

back 65

Answer:

e. 0

front 66

What is the wavelength of a photon that has an energy of J? ( c = 2.998 × 10 8 m/s, h = 6.626 × 10 -34 J·s)

a. ​ ​1.31912x10-1 nm

b. ​ 6.6405070933X1034nm

c. ​451 nm

d. 8.74048912x10-36 ​ nm

back 66

Answer:

c. ​451 nm

front 67

Of the following transitions in the Bohr hydrogen atom, the ________ transition results in the emission of the highest-energy photon.

n = 6 → n = 4

n = 2 → n = 7

n = 4 → n = 6

n = 1 → n = 4

All transitions emit photons of equivalent energy.

back 67

Answer:

n = 6 → n = 4

front 68

How many quantum numbers are necessary to designate a particular electron in an atom?

3

4

2

1

5

back 68

Answer: 4

front 69

How many different values of ml are possible in the 4f sublevel?

a. 3

b. 5

c. 7

d. 1

e. 2

back 69

Answer:

c. 7

front 70

Which one of the following is an incorrect subshell notation?

4f

2d

3s

2p

3d

back 70

Answer: 2d

front 71

The angular momentum quantum number (l) value of 2 indicates the ________ subshell.

d

f

s

p

0.5

back 71

Answer: d

front 72

The frequency of a photon that has an energy of 3.7 x 10-18 J is ________ s-1.

5.6 x 1015

1.8 x 10-16

2.5 x 10-15

5.4 x 10-8

2.5 x 1015

back 72

Answer:

5.6 x 1015

front 73

The largest principal quantum number in the ground state electron configuration of barium is ________.

1

2

6

4

5

back 73

Answer: 6

front 74

The 4d subshell in the ground state of atomic xenon contains ________ electrons.

2

6

8

10

36

back 74

Answer: 10

front 75

How many electrons can be described by the quantum numbers n = 3, l = 3, m l = −2?

e. 2

a. 10

b. 14

c. 0

d. 7

e. 2

back 75

Answer:

c. 0

front 76

What is the de Broglie wavelength (m) of a 25-g object moving at a speed of 5.0 m/s?

Answers:

1.9 x 1032 m

5.3 x 10-33 m

6.6 x 10-36 m

3.32 x 10-36 m

3.02 x 1045 m

back 76

Selected Answer:

5.3 x 10-33 m

front 77

The principal quantum number for the outermost electrons in a Te atom in the ground state is ________.

3

4

5

6

7

back 77

Answer: 5

front 78

The elements in the ________ period of the periodic table have a core-electron configuration that is the same as the electron configuration of neon.

first

second

third

fourth

fifth

back 78

Answer: third

front 79

Which one of the following represents an acceptable set of quantum numbers for an electron in an atom? (arranged as n, l, ml, and ms)

3, 0, 0, -1/2

3, -1, -4, 1/2

3, -3, 1, -1/2

0, 2, 1, 0

3, 3, 4, 3

back 79

Answers:

3, 0, 0, -1/2

front 80

What is the wavelength of light (nm) that has a frequency of 6.44 x 1013 s-1?

4660 nm

6490 nm

4.66 x 10-8 nm

6.49 x 10-8 nm

932 nm

back 80

Answer:

4660 nm

front 81

What is the frequency (s−1) of electromagnetic radiation that has a wavelength of 5.2 m?

a. 1.3x1034s−1

b. 5.7x107 s−1

c. 0.19 s−1

back 81

Answer:

b. 5.7x107 s−1

front 82

How many different principal quantum numbers can be found in the ground-state electron configuration of nickel?

2

3

4

5

6

back 82

Answer: 4

front 83

According to the Heisenberg Uncertainty Principle, it is impossible to know precisely both the position and the ________ of an electron.

mass

color

momentum

shape

charge

back 83

Answer: momentum

front 84

How many p-orbitals are occupied in a O atom?

5

6

0

3

1

back 84

Answer: 3

front 85

What is the energy of a photon of electromagnetic radiation with a wavelength of 117.6 nm? ( c = 2.998 × 10 8 m/s, h = 6.626 × 10 -34 J·s)

a. 2.5493197279​ x10-18 J

b. ​ 1.6991792517x10-18J

c. 7.792176x10-41​ J

back 85

Answer:

b.1.6991792517x10-18J

front 86

The complete electron configuration of sulfur, element 16, is ________.

1s22s22p63s23p4

1s22s22p103s2

1s42s42p63s2

1s42s42p8

1s62s62p23s2

back 86

Answer:

1s22s22p63s23p4

front 87

Which of the following elements has a ground-state electron configuration different from the predicted one?

Cu

Ca

Xe

Cl

Ti

back 87

Answer: Cu

front 88

A ________ orbital is degenerate with a 5dz2 in a many-electron atom.

5pz

4dz2

5s

5dxy

4dzz

back 88

Answer:

5dxy

front 89

How many quantum numbers are necessary to designate a particular electron in an atom?

3

4

2

1

5

back 89

Answer: 4