front 1 Which element is oxidized in the reaction below? A) C | back 1 D |
front 2 Which element is oxidized in the reaction below? A) Cr | back 2 D |
front 3 Which element is oxidized in the reaction below? A) H | back 3 B |
front 4 Which of the following reactions is a redox reaction? (a) K2CrO4 + BaCl2 → BaCrO4 + 2KCl A) (a) only | back 4 C |
front 5 Which one of the following reactions is a redox reaction? | back 5 D |
front 6 Which substance is the oxidizing agent in the following
reaction? A) HNO3 | back 6 A |
front 7 What is the coefficient of the permanganate ion when the following
equation is balanced? A) 1 | back 7 B |
front 8 What is the coefficient of the dichromate ion when the following
equation is balanced? A) 1 | back 8 A |
front 9 What is the coefficient of Fe3+ when the following
equation is balanced? A) 1 | back 9 B |
front 10 Which transformation could take place at the anode of an
electrochemical cell? | back 10 E |
front 11 The purpose of the salt bridge in an electrochemical cell is to
________. | back 11 A |
front 12 Which transformation below is an example of an oxidation in an
electrochemical cell? | back 12 C |
front 13 Which transformation could take place at the cathode of an
electrochemical cell? | back 13 D |
front 14 Which of the halogens in Table 20.1 is the strongest oxidizing
agent? | back 14 C |
front 15 Which one of the following types of elements is most likely to be a
good oxidizing agent? | back 15 E |
front 16 Which one of the following is the best oxidizing agent? | back 16 C |
front 17 Which of the following reactions will occur spontaneously as
written? | back 17 D |
front 18 Which of the following reactions will occur spontaneously as
written? | back 18 E |
front 19 Consider an electrochemical cell based on the reaction: 2H+ (aq) + Sn (s) → Sn2+ (aq) + H2 (g) Which of the following actions would change the measured cell
potential? | back 19 E |
front 20 Consider an electrochemical cell based on the reaction: | back 20 B |
front 21 What is the anode in an alkaline battery? | back 21 C |
front 22 What is the cathode in an alkaline battery? | back 22 A |
front 23 What is being reduced at the cathode in the hydrogen fuel
cell? | back 23 A |
front 24 In a lead-acid battery, the electrodes are consumed. In this battery,
________. | back 24 A |
front 25 Which of the statements about cathodic protection of a metal pipe
against corrosion is correct? | back 25 A |
front 26 One of the differences between a voltaic cell and an electrolytic
cell is that in an electrolytic cell, ________. | back 26 C |
front 27 The loss of electrons by an element is called ________. | back 27 D |
front 28 Which element is oxidized in the following reaction? Cr2O72- + 6S2O32- + 14H+ → 2Cr3+ + 3S4O62- + 7H2O A) S4O62-
| back 28 E |
front 29 Which element is reduced in the following reaction? Cr2O72- + 6S2O32- + 14H+ → 2Cr3+ + 3S4O62- + 7H2O A) H | back 29 B |
front 30 ________ is the reducing agent in the reaction
below. A) Cr2O72-
| back 30 B |
front 31 ________ is the reducing agent in the reaction below. A) Cl2 | back 31 D |
front 32 ________ is the oxidizing agent in the reaction below. A) Na+ | back 32 E |
front 33 Which substance is serving as the oxidizing agent in the following
reaction? A) H2O | back 33 C |
front 34 Which substance is the oxidizing agent in the reaction below? A) Pb | back 34 D |
front 35 Which substance does not undergo oxidation or reduction in the
reaction below? A) Pb | back 35 B |
front 36 What is the oxidation number of chromium in K2Cr2O7? | back 36 C |
front 37 What is the oxidation number of oxygen in H2O2? | back 37 D |
front 38 What is the oxidation number of manganese in KMnO4? | back 38 C |
front 39 What is the oxidation number of manganese in MnO2? | back 39 D |
front 40 What is the oxidation number of oxygen in K2O2? | back 40 C |
front 41 ________ electrons appear in the following half-reaction when it is balanced. S4O62- → 2S2O32- A) 6 | back 41 B |
front 42 The balanced half-reaction in which chlorine gas is reduced to the
aqueous chloride ion is a ________ process. | back 42 B |
front 43 The balanced half-reaction in which dichromate ion is reduced to
chromium metal is a ________ process. | back 43 E |
front 44 The balanced half-reaction in which ethanol, CH3CH2OH, is oxidized to
ethanoic acid, CH3COOH. | back 44 C |
front 45 The balanced half-reaction in which sulfate ion is reduced to sulfite
ion is a ________ process. | back 45 C |
front 46 The electrode at which oxidation occurs is called the
________. | back 46 D |
front 47 The half-reaction occurring at the anode in the balanced reaction shown below is ________. 3MnO4- (aq) + 24H+ (aq) + 5Fe (s) → 3Mn2+ (aq) + 5Fe3+ (aq) + 12H2O (l) A) MnO4- (aq) + 8H+ (aq) + 5e- → Mn2+ (aq) + 4H2O
(l) | back 47 C |
front 48 The half-reaction occurring at the cathode in the balanced reaction shown below is ________. 3MnO4- (aq) + 24H+ (aq) + 5Fe (s) → 3Mn2+ (aq) + 5Fe3+ (aq) + 12H2O (l) A) MnO4- (aq) + 8H+ (aq) + 5 → Mn2+ (aq) + 4H2O
(l) | back 48 A |
front 49 In a voltaic cell, electrons flow from the ________ to the
________. | back 49 E |
front 50 The reduction half reaction occurring in the standard hydrogen
electrode is ________. | back 50 D |
front 51 1V = ________. | back 51 D |
front 52 The less ________ the value of E°red, the lower the driving force for
reduction. | back 52 C |
front 53 The standard cell potential (E°cell) for the voltaic cell based on
the reaction below is ________ V. A) +0.46 | back 53 B |
front 54 The standard cell potential (E°cell) for the voltaic cell based on the reaction below is ________ V. Cr (s) + 3Fe3+ (aq) → 3Fe2+ (aq) + Cr3+ (aq) A) -1.45 | back 54 C |
front 55 The standard cell potential (E°cell) for the voltaic cell based on
the reaction below is ________ V. A) +0.30 | back 55 A |
front 56 The standard cell potential (E°cell) for the voltaic cell based on
the reaction below is ________ V. A) +1.94 | back 56 B |
front 57 The relationship between the change in Gibbs free energy and the emf
of an electrochemical cell is given by ________. | back 57 C |
front 58 The standard cell potential (E°cell) of the reaction below is +0.126
V. The value of ΔG for the reaction is ________ kJ/mol. A) -24.3 | back 58 A |
front 59 The standard cell potential (E°cell) of the reaction below is -0.55
V. The value of ΔG for the reaction is ________ J/mol. A) 0.54 | back 59 D |
front 60 The standard cell potential (E°cell) of the reaction below is -0.34
V. The value of ΔG for the reaction is ________ kJ/mol. A) -0.34 | back 60 B |
front 61 The standard cell potential (E°cell) of the reaction below is +1.34
V. The value of ΔG for the reaction is ________ kJ/mol. A) -24.3 | back 61 E |
front 62 The lead-containing reactant(s) consumed during recharging of a
lead-acid battery is/are ________. | back 62 C |
front 63 Galvanized iron is iron coated with ________. | back 63 B |
front 64 Corrosion of iron is retarded by ________. | back 64 B |
front 65 What is the oxidation number of bromine in the HBrO molecule? | back 65 A |
front 66 What is the oxidation number of nitrogen in the NH2OH
molecule? | back 66 A |
front 67 What is the oxidation number of sulfur in the S2O32–
ion? | back 67 A |
front 68 Which substance is the oxidizing agent in the reaction below? A) HI | back 68 A |
front 69 Which element is reduced in the reaction below? A) Cr | back 69 A |
front 70 Which element is oxidized in the reaction below? A) I | back 70 A |
front 71 Which element is reduced in the following reaction? A) N | back 71 A |
front 72 What is the oxidation number of phosphorous in the PH3
molecule? | back 72 A |
front 73 What is the correct coefficient for the electrons in the following half-reaction: Ni6+ + ___e– → Ni A) 6 | back 73 A |
front 74 In the galvanic cell using the redox reaction below, the reduction half-reaction is ________. Zn (s) + Cu2+ (aq) → Zn2+ (aq) + Cu (s) A) Cu2+ + 2e– → Cu | back 74 A |
front 75 In the electrochemical cell using the redox reaction below, the cathode half-reaction is ________. 2H+ (s) + Sn (s) → Sn2+ (aq) + H2 (g) A) 2H+ + 2e– → H2 | back 75 A |
front 76 In the electrochemical cell using the redox reaction below, the oxidation half reaction is ________. Sn4+ (aq) + Fe (s) → Sn2+ (aq) + Fe2+ (aq) A) Sn4+ + 2e– → Sn2+ | back 76 B |
front 77 The standard cell potential (E°) of a voltaic cell constructed using the cell reaction below is 0.76 V: Zn (s) + 2H+ (aq) → Zn2+ (aq) +H2 (g) With PH2 = 1.0 atm and [Zn2+] = 1.0 M, the cell potential
is 0.53 V. At 25 °C, the concentration of H+ in the cathode
compartment is ________ M. | back 77 A |
front 78 A voltaic cell is constructed with two silver-silver chloride electrodes, where the half-reaction is AgCl (s) + e- → Ag (s) + Cl- (aq) E° = +0.222 V The concentrations of chloride ion in the two compartments are
0.0100 M and 1.55 M, respectively. At 25 °C, the cell emf is ________
V. | back 78 B |
front 79 The standard cell potential (E°cell) for the reaction below is +0.63
V. At 25 °C, the cell potential for this reaction is ________ V when
[Zn2+] = 3.0 M and [Pb2+] = 2.0 x
10-4 M. A) 0.51 | back 79 A |
front 80 The standard cell potential (E°cell) for the reaction below is +1.10
V. The cell potential for this reaction is ________ V when the
concentration of [Cu2+] = 1.0 x 10-5 M AND
[Zn2+] = 3.0 M. A) 1.42 | back 80 C |
front 81 A voltaic cell is constructed with two Zn2+-Zn electrodes, where the half-reaction is Zn2+ + 2e- → Zn (s) E° = -0.763 V The concentrations of zinc ion in the two compartments are 4.50 M
and 1.11 × 10-2 M, respectively. The cell emf is ________
V. | back 81 C |
front 82 The standard emf for the cell using the overall cell reaction below is +2.20 V: 2Al (s) + 3I2 (s) → 2Al3+ (aq) + 6I- (aq) The emf generated by the cell when [Al3+] = 3.5 ×
10-3 M and [I-] = 0.30 M is ________ V. | back 82 B |
front 83 The standard emf for the cell using the overall cell reaction below is +0.48 V: Zn (s) + Ni2+ (aq) → Zn2+ (aq) + Ni (s) The emf generated by the cell when [Ni2+] = 0.100 M and
[Zn2+] = 2.25 M is ________ V. | back 83 C |
front 84 How many kilowatt-hours of electricity are used to produce 4.50 kg of
magnesium in the electrolysis of molten MgCl2 with an applied emf of
5.00 V? | back 84 D |
front 85 The most useful ore of aluminum is bauxite, in which Al is present as
hydrated oxides, Al2O3 . xH2O. The number of kilowatt-hours
of electricity required to produce 3.00 kg of aluminum from
electrolysis of compounds from bauxite is ________ when the applied
emf is 4.50 V. | back 85 E |
front 86 The town of Natrium, West Virginia, derives its name from the sodium
produced in the electrolysis of molten sodium chloride (NaCl) mined
from ancient salt deposits. The number of kilowatt-hours of
electricity required to produce 4.50 kg of metallic sodium from the
electrolysis of molten NaCl(s) is ________ when the applied emf is
5.00 V. | back 86 A |
front 87 The electrolysis of molten AlCl3 for 2.50 hr with an electrical
current of 12.0 A produces ________ g of aluminum metal. | back 87 D |
front 88 How many seconds are required to produce 5.00 g of aluminum metal
from the electrolysis of molten AlCl3 with an electrical current of
15.0 A? | back 88 E |
front 89 How many minutes will it take to plate out 2.19 g of chromium metal
from a solution of Cr3+ using a current of 19.5 amps in an
electrolytic cell? | back 89 A |
front 90 What current (in A) is required to plate out 1.22 g of nickel from a
solution of Ni2+ in 0.50 hour? | back 90 C |
front 91 How many grams of Ca metal are produced by the electrolysis of molten
CaBr2 using a current of 30.0 amp for 8.0 hours? | back 91 D |
front 92 How many grams of Cu are obtained by passing a current of 12 A
through a solution of CuSO4 for 15 minutes? | back 92 B |
front 93 How many seconds are required to produce 1.0 g of silver metal by the
electrolysis of a AgNO3 solution using a current of 60 amps? | back 93 C |
front 94 How many grams of copper will be plated out by a current of 2.3 A
applied for 35 minutes to a 0.50 M solution of copper (II)
sulfate? | back 94 A |
front 95 How much time (min) will it require to plate out 4.56 g of Ni metal
from a solution of Ni2+ using a current of 35.5 amps in an
electrolytic cell? | back 95 D |
front 96 How many minutes will it take to plate out 16.22 g of Al metal from a
solution of Al3+ using a current of 14.6 amps in an
electrolytic cell? | back 96 D |
front 97 Based on standard reduction potentials, the most difficult species to reduce and the poorest oxidizing agent is ________. | back 97 lithium ion; Li+ |
front 98 At constant ________ and ________ the Gibbs free energy value is a measure of the spontaneity of a process. | back 98 temperature, pressure |
front 99 In the formula ΔG = -nFE, n is the ________. | back 99 number of electrons transferred in the reaction |
front 100 Define the Nernst equation. | back 100 the dependence of cell emf on concentration |
front 101 The potential (E) to move K+ from the extracellular fluid to the intracellular fluid necessitates work. The sign for this potential is ________. | back 101 negative |
front 102 The ________ of the alkaline battery is powdered zinc in a gel that contacts potassium hydroxide. | back 102 anode |
front 103 The major product of a ________ fuel cell is water. | back 103 hydrogen |
front 104 What is a galvanized iron nail? | back 104 when an iron nail is coated with a thin layer of zinc to protect against corrosion |
front 105 Define a coulomb. | back 105 the quantity of charge passing a point in a circuit in one second when the current is one ampere |
front 106 Calculate the number of grams of aluminum produced in 1.00 hour by electrolysis of AlCl3 at a current of 10.0 A. | back 106 3.36 |
front 107 The electrode where reduction occurs is called the anode. | back 107 false |
front 108 In a voltaic cell electrons flow from the anode to the cathode. | back 108 true |
front 109 When the cell potential is negative in a voltaic cell, the cell reaction will not proceed spontaneously. | back 109 true |
front 110 The standard reduction potential, E°red, is proportional to the stoichiometric coefficient. | back 110 false |
front 111 The standard reduction potential of X is 1.23 V and that of Y is -0.44 V; therefore X is oxidized by Y. | back 111 false |
front 112 The lithium ion battery has more energy per unit mass than nickel-cadmium batteries. | back 112 true |
front 113 In a half reaction, the amount of a substance that is reduced or oxidized is directly proportional to the number of electrons generated in the cell. | back 113 true |
front 114 The amount of a substance that is reduced or oxidized is inversely proportional to the number of electrons produced in a cells half reaction. | back 114 false |