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Central Science: Chapter 20

front 1

Which element is oxidized in the reaction below?
Fe(CO)5 (l) + 2HI (g) → Fe(CO)4I2 (s) + CO (g) + H2 (g)

A) C
B) O
C) H
D) Fe
E) I

back 1

D

front 2

Which element is oxidized in the reaction below?
Fe2+ + H+ + Cr2O72- → Fe3+ + Cr3+ + H2O

A) Cr
B) O
C) H
D) Fe

back 2

D

front 3

Which element is oxidized in the reaction below?
I- + MnO4- + H+ → I2 + MnO2 + H2O

A) H
B) I
C) O
D) Mn

back 3

B

front 4

Which of the following reactions is a redox reaction?

(a) K2CrO4 + BaCl2 → BaCrO4 + 2KCl
(b) Pb22+ + 2Br- → PbBr
(c) Cu + S → CuS

A) (a) only
B) (b) only
C) (c) only
D) (a) and (c)
E) (b) and (c)

back 4

C

front 5

Which one of the following reactions is a redox reaction?
A) NaOH + HCl → NaCl + H2O
B) Pb2+ + 2Cl- → PbCl2
C) AgNO3 + HCl → HNO3 + AgCl
D) None of the above is a redox reaction.

back 5

D

front 6

Which substance is the oxidizing agent in the following reaction?
Fe2S3 + 12HNO3 → 2Fe(NO3)3 + 3S + 6NO2 + 6H2O

A) HNO3
B) S
C) NO2
D) Fe2S3
E) H2O

back 6

A

front 7

What is the coefficient of the permanganate ion when the following equation is balanced?
MnO4- + Br- → Mn2+ + Br2 (acidic solution)

A) 1
B) 2
C) 3
D) 5
E) 4

back 7

B

front 8

What is the coefficient of the dichromate ion when the following equation is balanced?
Fe2+ + Cr2O72- → Fe3+ + Cr3+ (acidic solution)

A) 1
B) 2
C) 3
D) 5
E) 6

back 8

A

front 9

What is the coefficient of Fe3+ when the following equation is balanced?
CN- + Fe3+ → CNO- + Fe2+ (basic solution)

A) 1
B) 2
C) 3
D) 4
E) 5

back 9

B

front 10

Which transformation could take place at the anode of an electrochemical cell?
A) Cr2O72- → Cr2+
B) F2 to F-
C) O2 to H2O
D) HAsO2 to As
E) None of the above could take place at the anode.

back 10

E

front 11

The purpose of the salt bridge in an electrochemical cell is to ________.
A) maintain electrical neutrality in the half-cells via migration of ions
B) provide a source of ions to react at the anode and cathode
C) provide oxygen to facilitate oxidation at the anode
D) provide a means for electrons to travel from the anode to the cathode
E) provide a means for electrons to travel from the cathode to the anode

back 11

A

front 12

Which transformation below is an example of an oxidation in an electrochemical cell?
A) CO2 → C2O42-
B) VO2+ → VO2+
C) NO → NO3-
D) H2AsO4 → H3AsO3
E) O2 → H2O2

back 12

C

front 13

Which transformation could take place at the cathode of an electrochemical cell?
A) MnO2 → MnO4-
B) Br2 → BrO3-
C) NO → HNO2
D) HSO4- → H2SO3
E) Mn2+ → MnO4-

back 13

D

front 14

Which of the halogens in Table 20.1 is the strongest oxidizing agent?
A) Cl2
B) Br2
C) F2
D) I2
E) All of the halogens have equal strength as oxidizing agents.

back 14

C

front 15

Which one of the following types of elements is most likely to be a good oxidizing agent?
A) alkali metals
B) lanthanides
C) alkaline earth elements
D) transition elements
E) halogens

back 15

E

front 16

Which one of the following is the best oxidizing agent?
A) H2
B) Na
C) O2
D) Li
E) Ca

back 16

C

front 17

Which of the following reactions will occur spontaneously as written?
A) Sn4+ (aq) + Fe3+ (aq) → Sn2+ (aq) + Fe2+ (aq)
B) 3Fe (s) + 2Cr3+ (aq) → 2Cr (s) + 3Fe2+ (aq)
C) Sn4+ (aq) + Fe2+ (aq) → Sn2+ (aq) + Fe (s)
D) 3Sn4+ (aq) + 2Cr (s) → 2Cr3+ (aq) + 3Sn2+ (aq)
E) 3Fe2+ (aq) → Fe (s) + 2Fe3+ (aq)

back 17

D

front 18

Which of the following reactions will occur spontaneously as written?
A) 3Fe2+ (aq) + Cr3+ (aq) → Cr (s) + 3Fe3+ (aq)
B) 2Cr3+ (aq) + 3Sn2+ (aq) → 3Sn4+ (aq) + 2Cr (s)
C) Sn4+ (aq) + Fe2+ (s) → Sn2+ (aq) + Fe (s)
D) Sn2+ (aq) + Fe2+ (s) → Sn4+ (aq) + Fe3+ (aq)
E) 2Cr (s) + 3Fe2+ (s) → 3Fe (s) + 2Cr3+ (aq)

back 18

E

front 19

Consider an electrochemical cell based on the reaction:

2H+ (aq) + Sn (s) → Sn2+ (aq) + H2 (g)

Which of the following actions would change the measured cell potential?
A) increasing the pH in the cathode compartment
B) lowering the pH in the cathode compartment
C) increasing the [Sn2+] in the anode compartment
D) increasing the pressure of hydrogen gas in the cathode compartment
E) Any of the above will change the measure cell potential.

back 19

E

front 20

Consider an electrochemical cell based on the reaction:
2H+ (aq) + Sn (s) → Sn2+ (aq) + H2 (g)
Which of the following actions would not change the measured cell potential?
A) lowering the pH in the cathode compartment
B) addition of more tin metal to the anode compartment
C) increasing the tin (II) ion concentration in the anode compartment
D) increasing the pressure of hydrogen gas in the cathode compartment
E) Any of the above will change the measured cell potential.

back 20

B

front 21

What is the anode in an alkaline battery?
A) MnO2
B) KOH
C) Zn powder
D) Mn2O3
E) Pt

back 21

C

front 22

What is the cathode in an alkaline battery?
A) MnO2
B) KOH
C) Zn powder
D) Mn2O3
E) Pt

back 22

A

front 23

What is being reduced at the cathode in the hydrogen fuel cell?
A) O2
B) KOH
C) Li
D) H2
E) Pt

back 23

A

front 24

In a lead-acid battery, the electrodes are consumed. In this battery, ________.
A) the anode is Pb
B) the anode is PbSO4
C) the anode is PbO2
D) the cathode is PbSO4
E) the cathode is Pb

back 24

A

front 25

Which of the statements about cathodic protection of a metal pipe against corrosion is correct?
A) The metal pipe is protected by attaching an active metal to make the pipe the cathode in an electrochemical cell
B) The metal pipe is protected by coating the pipe with another metal whose standard reduction potential is less negative than that of the pipe
C) The metal pipe is protected by attaching a dry cell to reduce any metal ions which might be formed
D) The metal pipe is protected by attaching an active metal to make the pipe the anode in an electrochemical cell
E) The metal pipe is protected by coating the pipe with a fluoropolymer to act as a source of fluoride ion (since the latter is so hard to oxidize)

back 25

A

front 26

One of the differences between a voltaic cell and an electrolytic cell is that in an electrolytic cell, ________.
A) an electric current is produced by a chemical reaction
B) electrons flow toward the anode
C) a nonspontaneous reaction is forced to occur
D) O2 gas is produced at the cathode
E) oxidation occurs at the cathode

back 26

C

front 27

The loss of electrons by an element is called ________.
A) fractionation
B) reduction
C) disproportionation
D) oxidation
E) sublimation

back 27

D

front 28

Which element is oxidized in the following reaction?

Cr2O72- + 6S2O32- + 14H+ → 2Cr3+ + 3S4O62- + 7H2O

A) S4O62-
B) Cr
C) H
D) O
E) S

back 28

E

front 29

Which element is reduced in the following reaction?

Cr2O72- + 6S2O32- + 14H+ → 2Cr3+ + 3S4O62- + 7H2O

A) H
B) Cr
C) O
D) S
E) S4O62-

back 29

B

front 30

________ is the reducing agent in the reaction below.
Cr2O72- + 6S2O32- + 14H+ → 2Cr3+ + 3S4O62- + 7H2O

A) Cr2O72-
B) S2O32-
C) H+
D) Cr3+
E) S4O62-

back 30

B

front 31

________ is the reducing agent in the reaction below.
Na(s) + 2Cl2(g) → 2NaCl(s)

A) Cl2
B) NaCl
C) Na+
D) Na
E) Cl-

back 31

D

front 32

________ is the oxidizing agent in the reaction below.
Na(s) + 2Cl2(g) → 2NaCl(s)

A) Na+
B) Cl-
C) Na
D) NaCl
E) Cl2

back 32

E

front 33

Which substance is serving as the oxidizing agent in the following reaction?
CH4(g) + 2O2(g) → CO2(g) + 2H2O(g)

A) H2O
B) CH4
C) O2
D) CO2
E) The reaction above is not a redox reaction

back 33

C

front 34

Which substance is the oxidizing agent in the reaction below?
Pb + PbO2 + 2H2SO4 → 2PbSO4 + 2H2O

A) Pb
B) PbSO4
C) H2SO4
D) PbO2
E) H2O

back 34

D

front 35

Which substance does not undergo oxidation or reduction in the reaction below?
Pb + PbO2 + 2H2SO4 → 2PbSO4 + 2H2O

A) Pb
B) H2SO4
C) PbO2
D) PbSO4
E) The reaction above is not a redox reaction

back 35

B

front 36

What is the oxidation number of chromium in K2Cr2O7?
A) +3
B) +12
C) +6
D) +7
E) +14

back 36

C

front 37

What is the oxidation number of oxygen in H2O2?
A) 0
B) +1
C) +2
D) -1
E) -2

back 37

D

front 38

What is the oxidation number of manganese in KMnO4?
A) +1
B) +2
C) +7
D) +4
E) +5

back 38

C

front 39

What is the oxidation number of manganese in MnO2?
A) +3
B) +2
C) +1
D) +4
E) +7

back 39

D

front 40

What is the oxidation number of oxygen in K2O2?
A) -2
B) +1
C) -1
D) +2
E) -1/2

back 40

C

front 41

________ electrons appear in the following half-reaction when it is balanced.

S4O62- → 2S2O32-

A) 6
B) 2
C) 4
D) 1
E) 3

back 41

B

front 42

The balanced half-reaction in which chlorine gas is reduced to the aqueous chloride ion is a ________ process.
A) one-electron
B) two-electron
C) four-electron
D) three-electron
E) six-electron

back 42

B

front 43

The balanced half-reaction in which dichromate ion is reduced to chromium metal is a ________ process.
A) two-electron
B) six-electron
C) three-electron
D) four-electron
E) twelve-electron

back 43

E

front 44

The balanced half-reaction in which ethanol, CH3CH2OH, is oxidized to ethanoic acid, CH3COOH.
is a ________ process.
A) twelve-electron
B) three-electron
C) four-electron
D) six-electron
E) two-electron

back 44

C

front 45

The balanced half-reaction in which sulfate ion is reduced to sulfite ion is a ________ process.
A) four-electron
B) one-electron
C) two-electron
D) three-electron
E) six-electron

back 45

C

front 46

The electrode at which oxidation occurs is called the ________.
A) oxidizing agent
B) cathode
C) reducing agent
D) anode
E) voltaic cell

back 46

D

front 47

The half-reaction occurring at the anode in the balanced reaction shown below is ________.

3MnO4- (aq) + 24H+ (aq) + 5Fe (s) → 3Mn2+ (aq) + 5Fe3+ (aq) + 12H2O (l)

A) MnO4- (aq) + 8H+ (aq) + 5e- → Mn2+ (aq) + 4H2O (l)
B) 2MnO4- (aq) + 12H+ (aq) + 6e- → 2Mn2+ (aq) + 3H2O (l)
C) Fe (s) → Fe3+ (aq) + 3e-
D) Fe (s) → Fe2+ (aq) + 2e-
E) Fe2+ (aq) → Fe3+ (aq) + e-

back 47

C

front 48

The half-reaction occurring at the cathode in the balanced reaction shown below is ________.

3MnO4- (aq) + 24H+ (aq) + 5Fe (s) → 3Mn2+ (aq) + 5Fe3+ (aq) + 12H2O (l)

A) MnO4- (aq) + 8H+ (aq) + 5 → Mn2+ (aq) + 4H2O (l)
B) 2MnO4- (aq) + 12H+ (aq) + 6e- → 2Mn2+ (aq) + 3H2O (l)
C) Fe (s) → Fe3+ (aq) + 3e-
D) Fe (s) → Fe2+ (aq) + 2e-
E) Fe2+ (aq) → Fe3+ (aq) + e-

back 48

A

front 49

In a voltaic cell, electrons flow from the ________ to the ________.
A) salt bride, anode
B) anode, salt bridge
C) cathode, anode
D) salt bridge, cathode
E) anode, cathode

back 49

E

front 50

The reduction half reaction occurring in the standard hydrogen electrode is ________.
A) H2 (g, 1 atm) → 2H+ (aq, 1M) + 2e-
B) 2H+ (aq) + 2O → H2O (l)
C) O2 (g) + 4H+ (aq) + 4e- → 2H2O (l)
D) 2H+ (aq, 1M) + 2e- → H2 (g, 1 atm)
E) 2H+ (aq, 1M) + Cl2 (aq) → 2HCl (aq)

back 50

D

front 51

1V = ________.
A) 1 amp ∙ s
B) 1 J/s
C) 96485 C
D) 1 J/C
E) 1 C/J

back 51

D

front 52

The less ________ the value of E°red, the lower the driving force for reduction.
A) negative
B) exothermic
C) positive
D) endothermic
E) extensive

back 52

C

front 53

The standard cell potential (E°cell) for the voltaic cell based on the reaction below is ________ V.
Sn2+ (aq) + 2Fe3+ (aq) → 2Fe2+ (aq) + Sn4+ (aq)

A) +0.46
B) +0.617
C) +1.39
D) -0.46
E) +1.21

back 53

B

front 54

The standard cell potential (E°cell) for the voltaic cell based on the reaction below is ________ V.

Cr (s) + 3Fe3+ (aq) → 3Fe2+ (aq) + Cr3+ (aq)

A) -1.45
B) +2.99
C) +1.51
D) +3.05
E) +1.57

back 54

C

front 55

The standard cell potential (E°cell) for the voltaic cell based on the reaction below is ________ V.
2Cr (s) + 3Fe2+ (aq) → 3Fe (s) + 2Cr3+ (aq)

A) +0.30
B) +2.80
C) +3.10
D) +0.83
E) -0.16

back 55

A

front 56

The standard cell potential (E°cell) for the voltaic cell based on the reaction below is ________ V.
3Sn4+ (aq) + 2Cr (s) → 2Cr3+ (aq) + 3Sn2+ (aq)

A) +1.94
B) +0.89
C) +2.53
D) -0.59
E) -1.02

back 56

B

front 57

The relationship between the change in Gibbs free energy and the emf of an electrochemical cell is given by ________.
A) ΔG = -nF/E
B) ΔG = -E/nF
C) ΔG = -nFE
D) ΔG = -nRTF
E) ΔG = -nF/ERT

back 57

C

front 58

The standard cell potential (E°cell) of the reaction below is +0.126 V. The value of ΔG for the reaction is ________ kJ/mol.
Pb (s) + 2H+(aq) → Pb2+ (aq) + H2 (g)

A) -24.3
B) +24.3
C) -12.6
D) +12.6
E) -50.8

back 58

A

front 59

The standard cell potential (E°cell) of the reaction below is -0.55 V. The value of ΔG for the reaction is ________ J/mol.
I2 (s) + 2Br- (aq) → 2I- (aq) + Br2 (l)

A) 0.54
B) 0.55
C) 5.5 × 10-6
D) 1.1 × 105
E) none of the above

back 59

D

front 60

The standard cell potential (E°cell) of the reaction below is -0.34 V. The value of ΔG for the reaction is ________ kJ/mol.
Cu (s) + 2H+ (aq) → Cu2+ (aq) + H2 (g)

A) -0.34
B) +66
C) -130
D) +130
E) none of the above

back 60

B

front 61

The standard cell potential (E°cell) of the reaction below is +1.34 V. The value of ΔG for the reaction is ________ kJ/mol.
3 Cu (s) + 2 MnO4- (aq) + 8H+ (aq) → 3 Cu2+ (aq) + 2 MnO2 (s) + 4 H2O (l)

A) -24.3
B) +259
C) -259
D) +776
E) -776

back 61

E

front 62

The lead-containing reactant(s) consumed during recharging of a lead-acid battery is/are ________.
A) Pb (s) only
B) PbO2 (s) only
C) PbSO4 (s) only
D) both PbO2 (s) and PbSO4 (s)
E) both Pb (s) and PbO2 (s)

back 62

C

front 63

Galvanized iron is iron coated with ________.
A) magnesium
B) zinc
C) chromium
D) phosphate
E) iron oxide

back 63

B

front 64

Corrosion of iron is retarded by ________.
A) the presence of salts
B) high pH conditions
C) low pH conditions
D) both the presence of salts and high pH conditions
E) both the presence of salts and low pH conditions

back 64

B

front 65

What is the oxidation number of bromine in the HBrO molecule?
A) +1
B) +2
C) 0
D) -1
E) -2

back 65

A

front 66

What is the oxidation number of nitrogen in the NH2OH molecule?
A) -1
B) -2
C) -3
D) 0
E) +1

back 66

A

front 67

What is the oxidation number of sulfur in the S2O32– ion?
A) +2
B) +1
C) 0
D) -1
E) -2

back 67

A

front 68

Which substance is the oxidizing agent in the reaction below?
Fe(CO)5 (l) + 2HI (g) → Fe(CO)4I2 (s) + CO (g) + H2 (g)

A) HI
B) Fe(CO)5
C) Fe(CO)4I2
D) CO
E) H2

back 68

A

front 69

Which element is reduced in the reaction below?
Fe2+ + H+ + Cr2O72- → Fe3+ + Cr3+ + H2O

A) Cr
B) Fe
C) H
D) O

back 69

A

front 70

Which element is oxidized in the reaction below?
I- + MnO4- + H+ → I2 + MnO2 + H2O

A) I
B) Mn
C) O
D) H

back 70

A

front 71

Which element is reduced in the following reaction?
Fe2S3 + 12HNO3 → 2Fe(NO3)3 + 3S + 6NO2 + 6H2O

A) N
B) S
C) H
D) O
E) NO2

back 71

A

front 72

What is the oxidation number of phosphorous in the PH3 molecule?
A) -3
B) -4
C) -5
D) +1
E) 0

back 72

A

front 73

What is the correct coefficient for the electrons in the following half-reaction:

Ni6+ + ___e– → Ni

A) 6
B) 1
C) 2
D) 3
E) 5

back 73

A

front 74

In the galvanic cell using the redox reaction below, the reduction half-reaction is ________.

Zn (s) + Cu2+ (aq) → Zn2+ (aq) + Cu (s)

A) Cu2+ + 2e– → Cu
B) Zn → Zn2+ + 2e–
C) Cu2+ → Cu + 2e–
D) Zn + 2e– → Zn2+

back 74

A

front 75

In the electrochemical cell using the redox reaction below, the cathode half-reaction is ________.

2H+ (s) + Sn (s) → Sn2+ (aq) + H2 (g)

A) 2H+ + 2e– → H2
B) Sn → Sn2+ + 2e–
C) 2H+ → H2 + 2e–
D) Sn + 2e– → Sn2+
E) Sn + 2e- → H2

back 75

A

front 76

In the electrochemical cell using the redox reaction below, the oxidation half reaction is ________.

Sn4+ (aq) + Fe (s) → Sn2+ (aq) + Fe2+ (aq)

A) Sn4+ + 2e– → Sn2+
B) Fe → Fe2+ + 2e–
C) Sn4+ → Sn2+ + 2e–
D) Fe + 2e– → Fe2+
E) Fe + 2e- → Sn2+

back 76

B

front 77

The standard cell potential (E°) of a voltaic cell constructed using the cell reaction below is 0.76 V:

Zn (s) + 2H+ (aq) → Zn2+ (aq) +H2 (g)

With PH2 = 1.0 atm and [Zn2+] = 1.0 M, the cell potential is 0.53 V. At 25 °C, the concentration of H+ in the cathode compartment is ________ M.
A) 1.3 × 10-4
B) 1.7 × 10-8
C) 1.1 × 10-2
D) 7.7 × 103
E) 1.3 × 10-11

back 77

A

front 78

A voltaic cell is constructed with two silver-silver chloride electrodes, where the half-reaction is

AgCl (s) + e- → Ag (s) + Cl- (aq) E° = +0.222 V

The concentrations of chloride ion in the two compartments are 0.0100 M and 1.55 M, respectively. At 25 °C, the cell emf is ________ V.
A) 0.216
B) 0.130
C) 0.00143
D) 34.4
E) 0.228

back 78

B

front 79

The standard cell potential (E°cell) for the reaction below is +0.63 V. At 25 °C, the cell potential for this reaction is ________ V when [Zn2+] = 3.0 M and [Pb2+] = 2.0 x 10-4 M.
Pb2+ (aq) + Zn (s) → Zn2+ (aq) + Pb (s)

A) 0.51
B) 0.86
C) 0.40
D) 0.75
E) 0.63

back 79

A

front 80

The standard cell potential (E°cell) for the reaction below is +1.10 V. The cell potential for this reaction is ________ V when the concentration of [Cu2+] = 1.0 x 10-5 M AND [Zn2+] = 3.0 M.
Zn (s) + Cu2+ (aq) → Cu (s) + Zn2+ (aq)

A) 1.42
B) 1.26
C) 0.94
D) 0.78
E) 1.10

back 80

C

front 81

A voltaic cell is constructed with two Zn2+-Zn electrodes, where the half-reaction is

Zn2+ + 2e- → Zn (s) E° = -0.763 V

The concentrations of zinc ion in the two compartments are 4.50 M and 1.11 × 10-2 M, respectively. The cell emf is ________ V.
A) -1.88 × 10-3
B) -309
C) 0.0772
D) 0.154
E) -0.761

back 81

C

front 82

The standard emf for the cell using the overall cell reaction below is +2.20 V:

2Al (s) + 3I2 (s) → 2Al3+ (aq) + 6I- (aq)

The emf generated by the cell when [Al3+] = 3.5 × 10-3 M and [I-] = 0.30 M is ________ V.
A) 2.20
B) 2.28
C) 2.12
D) 2.36
E) 2.23

back 82

B

front 83

The standard emf for the cell using the overall cell reaction below is +0.48 V:

Zn (s) + Ni2+ (aq) → Zn2+ (aq) + Ni (s)

The emf generated by the cell when [Ni2+] = 0.100 M and [Zn2+] = 2.25 M is ________ V.
A) 0.56
B) 0.50
C) 0.44
D) 0.40
E) 0.52

back 83

C

front 84

How many kilowatt-hours of electricity are used to produce 4.50 kg of magnesium in the electrolysis of molten MgCl2 with an applied emf of 5.00 V?
A) 0.0201
B) 0.0496
C) 12.4
D) 49.6
E) 24.8

back 84

D

front 85

The most useful ore of aluminum is bauxite, in which Al is present as hydrated oxides, Al2O3 . xH2O. The number of kilowatt-hours of electricity required to produce 3.00 kg of aluminum from electrolysis of compounds from bauxite is ________ when the applied emf is 4.50 V.
A) 0.0249
B) 0.0402
C) 26.8
D) 13.4
E) 40.2

back 85

E

front 86

The town of Natrium, West Virginia, derives its name from the sodium produced in the electrolysis of molten sodium chloride (NaCl) mined from ancient salt deposits. The number of kilowatt-hours of electricity required to produce 4.50 kg of metallic sodium from the electrolysis of molten NaCl(s) is ________ when the applied emf is 5.00 V.
A) 26.2
B) 0.0381
C) 0.0262
D) 52.5
E) 13.1

back 86

A

front 87

The electrolysis of molten AlCl3 for 2.50 hr with an electrical current of 12.0 A produces ________ g of aluminum metal.
A) 90.7
B) 0.373
C) 2.80 × 10-3
D) 10.1
E) 30.2

back 87

D

front 88

How many seconds are required to produce 5.00 g of aluminum metal from the electrolysis of molten AlCl3 with an electrical current of 15.0 A?
A) 27.0
B) 9.00
C) 1.19E × 103
D) 2.90 × 105
E) 3.57 × 103

back 88

E

front 89

How many minutes will it take to plate out 2.19 g of chromium metal from a solution of Cr3+ using a current of 19.5 amps in an electrolytic cell?
A) 10.4
B) 625
C) 208
D) 3.47
E) 31.2

back 89

A

front 90

What current (in A) is required to plate out 1.22 g of nickel from a solution of Ni2+ in 0.50 hour?
A) 65.4
B) 8.02 × 103
C) 2.22
D) 12.9
E) 4.46

back 90

C

front 91

How many grams of Ca metal are produced by the electrolysis of molten CaBr2 using a current of 30.0 amp for 8.0 hours?
A) 17.9
B) 359
C) 0.0622
D) 179
E) 89.7

back 91

D

front 92

How many grams of Cu are obtained by passing a current of 12 A through a solution of CuSO4 for 15 minutes?
A) 0.016
B) 3.6
C) 7.1
D) 14
E) 1.8

back 92

B

front 93

How many seconds are required to produce 1.0 g of silver metal by the electrolysis of a AgNO3 solution using a current of 60 amps?
A) 5.4 × 104
B) 3.2 × 103
C) 15
D) 3.7 × 10-5
E) 30

back 93

C

front 94

How many grams of copper will be plated out by a current of 2.3 A applied for 35 minutes to a 0.50 M solution of copper (II) sulfate?
A) 1.6
B) 3.2
C) 1.8 × 10-2
D) 3.6 × 10-2
E) 0.019

back 94

A

front 95

How much time (min) will it require to plate out 4.56 g of Ni metal from a solution of Ni2+ using a current of 35.5 amps in an electrolytic cell?
A) 4.55
B) 3.52
C) 211
D) 7.04
E) 422

back 95

D

front 96

How many minutes will it take to plate out 16.22 g of Al metal from a solution of Al3+ using a current of 14.6 amps in an electrolytic cell?
A) 53.0
B) 66.2
C) 153
D) 199
E) 11900

back 96

D

front 97

Based on standard reduction potentials, the most difficult species to reduce and the poorest oxidizing agent is ________.

back 97

lithium ion; Li+

front 98

At constant ________ and ________ the Gibbs free energy value is a measure of the spontaneity of a process.

back 98

temperature, pressure

front 99

In the formula ΔG = -nFE, n is the ________.

back 99

number of electrons transferred in the reaction

front 100

Define the Nernst equation.

back 100

the dependence of cell emf on concentration

front 101

The potential (E) to move K+ from the extracellular fluid to the intracellular fluid necessitates work. The sign for this potential is ________.

back 101

negative

front 102

The ________ of the alkaline battery is powdered zinc in a gel that contacts potassium hydroxide.

back 102

anode

front 103

The major product of a ________ fuel cell is water.

back 103

hydrogen

front 104

What is a galvanized iron nail?

back 104

when an iron nail is coated with a thin layer of zinc to protect against corrosion

front 105

Define a coulomb.

back 105

the quantity of charge passing a point in a circuit in one second when the current is one ampere

front 106

Calculate the number of grams of aluminum produced in 1.00 hour by electrolysis of AlCl3 at a current of 10.0 A.

back 106

3.36

front 107

The electrode where reduction occurs is called the anode.

back 107

false

front 108

In a voltaic cell electrons flow from the anode to the cathode.

back 108

true

front 109

When the cell potential is negative in a voltaic cell, the cell reaction will not proceed spontaneously.

back 109

true

front 110

The standard reduction potential, E°red, is proportional to the stoichiometric coefficient.

back 110

false

front 111

The standard reduction potential of X is 1.23 V and that of Y is -0.44 V; therefore X is oxidized by Y.

back 111

false

front 112

The lithium ion battery has more energy per unit mass than nickel-cadmium batteries.

back 112

true

front 113

In a half reaction, the amount of a substance that is reduced or oxidized is directly proportional to the number of electrons generated in the cell.

back 113

true

front 114

The amount of a substance that is reduced or oxidized is inversely proportional to the number of electrons produced in a cells half reaction.

back 114

false