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Central Science: Chapter 16

front 1

According to the Arrhenius concept, an acid is a substance that ________.
A) is capable of donating one or more H+
B) causes an increase in the concentration of H+ in aqueous solutions
C) can accept a pair of electrons to form a coordinate covalent bond
D) reacts with the solvent to form the cation formed by autoionization of that solvent
E) tastes bitter

back 1

B

front 2

A Br∅nsted-Lowry base is defined as a substance that ________.
A) increases [H+] when placed in H2O
B) decreases [H+] when placed in H2O
C) increases [OH-] when placed in H2O
D) acts as a proton acceptor
E) acts as a proton donor

back 2

D

front 3

A Br∅nsted-Lowry acid is defined as a substance that ________.
A) increases Ka when placed in H2O
B) decreases [H+] when placed in H2O
C) increases [OH-] when placed in H2O
D) acts as a proton acceptor
E) acts as a proton donor

back 3

E

front 4

Which one of the following is a Br∅nsted-Lowry acid?
A) (CH3)3NH+
B) CH3COOH
C) HF
D) HNO2
E) all of the above

back 4

E

front 5

A substance that is capable of acting as both an acid and as a base is ________.
A) autosomal
B) conjugated
C) amphiprotic
D) saturated
E) miscible

back 5

C

front 6

Which one of the following is a Br∅nsted-Lowry base?
A) (CH3)3N
B) CH3COOH
C) HF
D) HNO2
E) none of the above

back 6

A

front 7

The molar concentration of hydronium ion in pure water at 25 °C is ________.
A) 0.00
B) 1.0 × 10-7
C) 1.0 × 10-14
D) 1.00
E) 7.00

back 7

B

front 8

The molar concentration of hydroxide ion in pure water at 25 °C is ________.
A) 1.00
B) 0.00
C) 1.0 × 10-14
D) 1.0 × 10-7
E) 7.00

back 8

D

front 9

The magnitude of Kw indicates that ________.
A) water autoionizes very slowly
B) water autoionizes very quickly
C) water autoionizes only to a very small extent
D) the autoionization of water is exothermic

back 9

C

front 10

Which one of the following statements regarding Kw is false?
A) pKw is 14.00 at 25 °C.
B) The value of Kw is always 1.0 × 10-14.
C) Kw changes with temperature.
D) The value of Kw shows that water is a weak acid.
E) Kw is known as the ion product of water.

back 10

B

front 11

The hydride ion, H-, is a stronger base than the hydroxide ion, OH-. The product(s) of the reaction of hydride ion with water is/are ________.
A) H3O+ (aq)
B) OH- (aq) + H2 (g)
C) OH- (aq) + 2H+ (aq)
D) no reaction occurs
E) H2O2 (aq)

back 11

B

front 12

Of the following acids, ________ is a strong acid.
A) HNO2
B) H2CO3
C) HNO3
D) HClO
E) HF

back 12

C

front 13

Of the following acids, ________ is not a strong acid.
A) HNO2
B) H2SO4
C) HNO3
D) HClO4
E) HCl

back 13

A

front 14

Of the following, ________ is a weak acid.
A) HF
B) HCl
C) HBr
D) HNO3
E) HClO4

back 14

A

front 15

Which one of the following is the weakest acid?
A) HF (Ka = 6.8 × 10-4)
B) HClO (Ka = 3.0 × 10-8)
C) HNO2 (Ka = 4.5 × 10-4)
D) HCN (Ka = 4.9 × 10-10)
E) Acetic acid (Ka = 1.8 × 10-5)

back 15

D

front 16

Of the acids in the table below, ________ is the strongest acid.

A) HOAc
B) HCHO2
C) HClO
D) HF
E) HOAc and HCHO2

back 16

D

front 17

The Ka of hypochlorous acid (HClO) is 3.0 × 10-8 at . What is the percent ionization of hypochlorous acid in a aqueous solution of HClO at
A) 4.5 × 10-8
B) 14
C) 2.1 × 10-5
D) 0.14
E) 1.4 × 10-3

back 17

D

front 18

Classify the following compounds as weak acids (W) or strong acids (S):

benzoic acid, nitric acid, acetic acid

A) W W W
B) S S S
C) S W W
D) W S S
E) W S W

back 18

E

front 19

Classify the following compounds as weak acids (W) or strong acids (S):

hydrocyanic acid, hydrofluoric acid, hydrobromic acid

A) S W W
B) S S S
C) W W S
D) W S S
E) W S W

back 19

C

front 20

Classify the following compounds as weak acids (W) or strong acids (S):

hydrobromic acid, hydrochloric acid, hydrofluoric acid

A) W W W
B) S S S
C) S W W
D) W S S
E) S S W

back 20

E

front 21

Classify the following compounds as weak acids (W) or strong acids (S):

nitric acid, perchloric acid, chloric acid

A) W W W
B) W S S
C) S S S
D) S W W
E) W S W

back 21

C

front 22

Ammonia is a ________.
A) weak acid
B) strong base
C) weak base
D) strong acid
E) salt

back 22

C

front 23

HA is a weak acid. Which equilibrium corresponds to the equilibrium constant Kb for A-?
A) HA (aq) + H2O (l) ⇌ H2A+ (aq) + OH-(aq)
B) A- (aq) + H3O+ (aq) ⇌ HA (aq) + H2O (l)
C) HA (aq) + OH- (aq) ⇌ H2O (l) + H+ (aq)
D) A- (aq) + H2O (l) ⇌ HA (aq) + OH- (aq)
E) A- (aq) + OH- (aq) ⇌ HOA2- (aq)

back 23

D

front 24

A- is a weak base. Which equilibrium corresponds to the equilibrium constant Ka for HA?
A) HA (aq) + H2O (l) ⇌ H2A+ (aq) + OH- (aq)
B) A- (aq) + H3O+ (aq) ⇌ HA (aq) + H2O (l)
C) HA (aq) + H2O (l) ⇌ H3O+ (aq) + A- (aq)
D) A- (aq) + H2O (l) ⇌ HA (aq) + OH- (aq)
E) A- (aq) + OH- (aq) ⇌ HOA2- (aq)

back 24

C

front 25

Classify the following compounds as weak bases (W) or strong bases (S):

ammonia, fluoride ion, sodium ion

A) S S S
B) S W W
C) W W W
D) W S S
E) W S W

back 25

C

front 26

Classify the following compounds as weak bases (W) or strong bases (S):

methylamine, carbonate ion, potassium ion

A) S S S
B) S W W
C) W S S
D) W W W
E) W S W

back 26

D

front 27

Using the data in the table, which of the conjugate bases below is the strongest base?

A) OAc-
B) C7H5O2-
C) NO2-
D) F-
E) OAc- and C7H5O2-

back 27

A

front 28

Using the data in the table, which of the conjugate bases below is the weakest base?

A) OAc-
B) C7H5O2-
C) NO2-
D) F-
E) OAc- and C7H5O2-

back 28

D

front 29

Using the data in the table, which of the conjugate bases below is the weakest base?

A) OAc-
B) CHO2-
C) ClO-
D) F-
E) OAc- and CHO2-

back 29

D

front 30

Using the data in the table, which of the conjugate bases below is the weakest base?

A) OAc-
B) CHO2-
C) ClO-
D) F-
E) OAc- and CHO2-

back 30

D

front 31

Using the data in the table, which of the conjugate acids below is the strongest acid?

A) HClO
B) HCO3-
C) H2S
D) NH3CH3+
E) H2S and HClO

back 31

C

front 32

Using the data in the table, which of the conjugate acids below is the strongest acid?

A) HClO
B) HCO3-
C) H2S
D) NH3CH3+
E) H2S and HClO

back 32

C

front 33

Using the data in the table, which of the conjugate acids below is the weakest acid?

A) NH4+
B) C5H5NH+
C) H3NOH+
D) NH3CH3+
E) NH4+ and NH3CH3+

back 33

D

front 34

Using the data in the table, which of the conjugate acids below is the weakest acid?

A) NH4+
B) C5H5NH+
C) NH3CH2CH3+
D) H3NOH+
E) NH4+ and NH3CH3+

back 34

C

front 35

Which of the following ions will act as a weak base in water?
A) OH-
B) Cl-
C) NO3-
D) ClO-
E) None of the above will act as a weak base in water.

back 35

D

front 36

Which of the following ions will act as a strong base in water?
A) HS-
B) F-
C) NO2-
D) ClO-
E) None of the above will act as a strong base in water.

back 36

E

front 37

Which of the following aqueous solutions has the highest [OH-]?
A) a solution with a pH of 3.0
B) a 1 × 10-4 M solution of HNO3
C) a solution with a pOH of 12.0
D) pure water
E) a 1 × 10-3 M solution of NH4Cl

back 37

D

front 38

Which of the following aqueous solutions has the lowest [OH-]?
A) a solution with a pH of 3.0
B) a 1 × 10-4 M solution of HNO3
C) a solution with a pOH of 12.0
D) pure water
E) a 1 × 10-3 M solution of NH4Cl

back 38

C

front 39

An aqueous solution of a particular compound has pH = 7.46. The compound is ________.
A) a weak base
B) a weak acid
C) a strong acid
D) a strong base
E) a salt

back 39

A

front 40

Of the following substances, an aqueous solution of ________ will form basic solutions.

NaHS, Cu(NO3)2, KHCO3, NaF

A) NaHS, Cu(NO3)2
B) KHCO3, NaHS
C) NaF only
D) NaF, KHCO3
E) NaHS, KHCO3 and NaF

back 40

E

front 41

Of the following substances, an aqueous solution of ________ will form basic solutions.

NH4Br, Pb(NO3)2, K2CO3, NaF

A) NH4Br, Pb(NO3)2
B) K2CO3, NH4Br
C) NaF only
D) NaF, K2CO3
E) NH4Br only

back 41

D

front 42

Of the compounds below, a 0.1 M aqueous solution of ________ will have the highest pH.
A) KCN, Ka of HCN = 4.0 × 10-10
B) NH4NO3, Kb of NH3 = 1.8 × 10-5
C) NaOAc, Ka of HOAc = 1.8 × 10-5
D) NaClO, Ka of HClO = 3.2 × 10-8
E) NaHS, Kb of HS- = 1.8 × 10-7

back 42

A

front 43

A 0.5 M solution of ________ has a pH of 7.0.
A) K2S
B) KF
C) KNO3
D) NH4Br
E) NaF

back 43

C

front 44

Which of the following acids will be the strongest?
A) H2SO4
B) HSO4-
C) H2SO3
D) H2SeO4
E) HSO3-

back 44

A

front 45

Of the following, which is the strongest acid?
A) HClO
B) HClO3
C) HClO2
D) HClO4
E) HIO

back 45

D

front 46

In the gas phase reaction below, NH3 is acting as a(n) ________.

A) Br∅nsted-Lowry acid
B) Br∅nsted-Lowry base
C) Lewis base
D) Lewis acid
E) Arrhenius acid

back 46

C

front 47

What is the conjugate acid of NH2-?
A) NH2+
B) NH3+
C) NH4+
D) NH3
E) NH4OH

back 47

D

front 48

What is the conjugate acid of HCO3-?
A) CO22-
B) H2CO3
C) HCO22-
D) CO32-
E) none of the above

back 48

D

front 49

The conjugate acid of SO42- is ________.
A) OH-
B) H2SO4
C) HSO4-
D) HSO42-
E) H3SO4+

back 49

C

front 50

The conjugate base of HPO42- is ________.
A) PO43-
B) H2PO4
C) H3PO4
D) H2PO4-
E) none of the above

back 50

A

front 51

The conjugate base of HSO4- is ________.
A) H2SO4
B) HSO4+
C) H+
D) SO42-
E) HSO3+

back 51

D

front 52

The conjugate base of CH3NH3+ is ________.
A) CH3NH2+
B) CH3NH2-
C) CH3NH+
D) CH3NH2
E) none of the above

back 52

D

front 53

What is the conjugate acid of OH-?
A) O2
B) H2O
C) O-
D) O2-
E) H3O+

back 53

B

front 54

What is the pH of an aqueous solution at 25.0 °C that contains 2.50 × 10-4 M hydronium ion?
A) 10.4
B) 4.00
C) 2.50
D) 3.60
E) 7.00

back 54

D

front 55

What is the pOH of an aqueous solution at 25.0 °C that contains 2.50 × 10-4 M hydronium ion?
A) 3.60
B) 4.00
C) 2.50
D) 10.4
E) 7.00

back 55

D

front 56

What is the pH of an aqueous solution at 25.0 °C that contains 1.35 × 10-8 M hydroxide ion?
A) 7.87
B) 8.00
C) 6.13
D) 1.35
E) 7.00

back 56

C

front 57

What is the pOH of an aqueous solution at 25.0 °C that contains 1.35 × 10-8 M hydroxide ion?
A) 6.13
B) 7.87
C) 1.35
D) 8.00
E) 7.00

back 57

B

front 58

Calculate the pOH of a solution at 25.0 °C that contains 2.95 × 10-12 M hydronium ions.
A) 12.00
B) 2.95
C) 7.00
D) 2.47
E) 11.53

back 58

D

front 59

Calculate the pH of a solution at 25.0 °C that contains 2.95 × 10-12 M hydronium ions.
A) 2.95
B) 11.53
C) 7.00
D) 12.00
E) 2.47

back 59

B

front 60

Calculate the concentration (in M) of hydronium ions in a solution at 25.0 °C with a pOH of 3.58.
A) 2.63 × 10-4
B) 2.63 × 1010
C) 3.80 × 10-11
D) 3.80 × 103
E) 1.00 × 10-7

back 60

C

front 61

Calculate the concentration (in M) of hydroxide ions in a solution at 25.0 °C with a pOH of 3.58.
A) 2.63 × 1010
B) 3.80 × 10-11
C) 1.00 × 10-7
D) 3.80 × 103
E) 2.63 × 10-4

back 61

E

front 62

An aqueous solution contains 0.500 M NaOH at 25.0 °C. The pH of the solution is ________.
A) 0.500
B) 13.70
C) 0.301
D) 7.00
E) 13.50

back 62

B

front 63

An aqueous solution contains 0.390 M HCl at 25.0 °C. The pH of the solution is ________.
A) 0.41
B) 0.390
C) 13.61
D) 13.59
E) 7.00

back 63

A

front 64

HZ is a weak acid. An aqueous solution of HZ is prepared by dissolving 0.020 mol of HZ in sufficient water to yield 1.0 L of solution. The pH of the solution was 4.93 at 25.0 °C. The Ka of HZ is ________.
A) 1.2 × 10-5
B) 6.9 × 10-9
C) 1.4 × 10-10
D) 9.9 × 10-2
E) 2.8 × 10-12

back 64

B

front 65

The pH of a 0.55 M aqueous solution of hypobromous acid, HBrO, at 25.0 °C is 4.48. What is the value of Ka for HBrO?
A) 2.0 × 10-9
B) 1.1 × 10-9
C) 6.0 × 10-5
D) 3.3 × 10-5
E) 3.0 × 104

back 65

A

front 66

The pH of a 0.25 M aqueous solution of hydrofluoric acid, HF, at 25.0 °C is 2.03. What is the value of Ka for HF?
A) 2.0 × 10-9
B) 1.1 × 10-9
C) 6.0 × 10-5
D) 3.5 × 10-4
E) none of the above

back 66

D

front 67

The pH of a 0.60 M aqueous solution of formic acid, HCHO2, at 25.0 °C is 1.98. What is the value of Ka for formic acid?
A) 2.0 × 10-5
B) 1.8 × 10-4
C) 6.0 × 10-5
D) 3.5 × 10-4
E) none of the above

back 67

B

front 68

A 0.22 M aqueous solution of the weak acid HA at 25.0 °C has a pH of 4.15. The value of Ka for HA is ________.
A) 7.1 × 10-5
B) 3.2 × 10-4
C) 2.2 × 10-1
D) 2.3 × 10-8
E) 3.2 × 104

back 68

D

front 69

The Ka of hypochlorous acid (HClO) is 3.00 x10-8. What is the pH at 25.0 °C of an aqueous solution that is 0.0200 M in HClO?
A) +2.45
B) -2.45
C) -9.22
D) +9.22
E) +4.61

back 69

E

front 70

The Ka of acetic acid (HC2H3O2) is 1.8 x 10-5. What is the pH at 25.0 °C of an aqueous solution that is 0.100 M in acetic acid?
A) +2.87
B) -2.87
C) -11.13
D) +11.13
E) +6.61

back 70

A

front 71

The acid-dissociation constants of sulfurous acid (H2SO3) are Ka1 = 1.7 × 10-2 and Ka2 = 6.4 x 10-8 at 25.0 °C. Calculate the pH of a 0.163 M aqueous solution of sulfurous acid.
A) 4.53
B) 1.28
C) 1.86
D) 6.21
E) 1.93

back 71

B

front 72

The acid-dissociation constants of phosphoric acid (H3PO4) are Ka1 = 7.5 × 10-3, Ka2 = 6.2 x 10-8, and Ka3 = 4.2 × 10-13 at 25.0 °C. What is the pH of a 2.5 M aqueous solution of phosphoric acid?
A) 1.82
B) 0.40
C) 2.51
D) 0.86
E) 0.13

back 72

D

front 73

The pH of a 0.25 M aqueous solution ammonia, NH3, at 25.0 °C is 9.50. What is the value of Kb for NH3?
A) 2.5 × 10-1
B) 4.0 × 10-19
C) 4.0 × 10-9
D) 3.2 × 10-5
E) none of the above

back 73

C

front 74

A 0.10 M aqueous solution of the weak base B at 25.0 °C has a pH of 8.00. The value of Kb for B is ________.
A) 1.0 × 10-15
B) 1.0 × 10-11
C) 1.0 × 10-6
D) 1.0 × 10-12
E) none of the above

back 74

B

front 75

A 0.14 M aqueous solution of the weak acid HA at 25.0 °C has a pH of 3.15. The value of Ka for HA is ________.
A) 7.08 × 10-4
B) 3.58 × 10-6
C) 5.01 × 10-7
D) 7.02 × 10-8
E) none of the above

back 75

B

front 76

An aqueous solution of NaF is prepared by dissolving 0.350 mol of NaF in sufficient water to yield 1.0 L of solution. The pH of the solution was 8.93 at 25.0 °C. The Kb of F- is ________.
A) 1.2 × 10-5
B) 2.1 × 10-10
C) 6.9 × 10-9
D) 2.8 × 10-12
E) 9.9 × 10-2

back 76

B

front 77

The pOH of a 0.10 M solution of a weak base is 4.18. What is the Kb for this base?
A) 8.8 × 10-8
B) 2.1 × 10-4
C) 6.6 × 10-4
D) 4.4 × 10-8
E) 2.0 × 10-5

back 77

D

front 78

Determine the pH of a 0.35 M aqueous solution of CH3NH2 (methylamine). The Kb of methylamine is 4X4 x 10-4.
A) 10.00
B) 3.86
C) 12.09
D) 1.96
E) 13.24

back 78

C

front 79

An aqueous basic solution has a concentration of 0.050 M and Kb is 4.4 × 10-4. What is the concentration of hydroxide ion in this solution (M)?
A) 2.2 × 10-5
B) 4.5 × 10-3
C) 2.9 × 10-3
D) 4.7 × 10-3
E) 0.050

back 79

B

front 80

An aqueous basic solution has a concentration of 0.050 M and Kb is 4.4 × 10-4. What is the concentration of hydronium ion in this solution (M)?
A) 2.2 × 10-13
B) 2.2 × 10-12
C) 2.9 × 10-13
D) 0.050
E) 4.5 × 10-13

back 80

B

front 81

The acid-dissociation constant, Ka, for an unknown acid HA is 4.57 × 10-3. What is the base-dissociation constant, Kb, for the unknown anion A-?
A) 5.43 × 10-5
B) 4.57 × 10-3
C) 7.81 × 10-6
D) 2.19 × 10-12
E) 2.19 × 102

back 81

D

front 82

The base-dissociation constant, Kb, for an unknown base is 1.4 x 10-9. The acid-dissociation constant, Ka, for the conjugate ion is ________.
A) 1.0 × 10-7
B) 7.1 × 10-6
C) 1.4 × 10-23
D) 1.4 × 10-5
E) 7.1 × 10-4

back 82

B

front 83

The Ka for HCN is 4.9 × 10-10. What is the value of Kb for CN-?
A) 2.0 × 10-5
B) 4.0 × 10-6
C) 4.9 × 104
D) 4.9 × 10-24
E) 2.0 × 109

back 83

A

front 84

Ka for HF is 7.0 × 10-4. Kb for the fluoride ion is ________.
A) 2.0 × 10-8
B) 1.4 × 10-11
C) 7.0 × 10-18
D) 7.0 × 10-4
E) 1.4 × 103

back 84

B

front 85

Ka for HA is 4.9 × 10-10. What is the pH of a 0.068 M aqueous solution of A-?
A) 11.07
B) 0.74
C) 2.96
D) 7.00
E) 13.24

back 85

A

front 86

Ka for arsenic acic, HAsO42-, is 7.5 × 10-12. What is the pH of a 0.15 M aqueous solution of AsO43-?
A) 7.97
B) 12.10
C) 8.04
D) 1.96
E) 6.00

back 86

B

front 87

The pH of a 0.15 M aqueous solution of NaBrO (the sodium salt of HBrO) is 10.7. What is the Ka for HBrO?
A) 8.9 × 10-4
B) 1.6 × 10-6
C) 1.3 × 10-12
D) 3.3 × 10-8
E) 6.0 × 10-9

back 87

E

front 88

The conjugate base of NH3 is ________.
A) NH2-
B) NH4+
C) NH2OH
D) H3O+
E) OH-

back 88

A

front 89

The conjugate base of H2PO4- is ________.
A) H3PO4
B) HPO42-
C) PO43-
D) H3O+
E) OH-

back 89

A

front 90

In acidic solution, ________.
A) [H3O+] > [OH-]
B) [H3O+] = [OH-]
C) [H3O+] < [OH-]
D) [O ] > 7.00
E) [ ] = 0M

back 90

A

front 91

Which solution below has the highest concentration of hydroxide ions?
A) pH = 12.5
B) pH = 11
C) pH = 8.3
D) pH = 6.0
E) pH = 3.0

back 91

A

front 92

Which solution below has the highest concentration of hydronium ions?
A) pH = 3.0
B) pH = 10
C) pH = 7.0
D) pH = 6.4
E) pH = 11.2

back 92

A

front 93

An aqueous solution at 25.0°C contains [H+] = 0.085 M. What is the pH of the solution?
A) 1.07
B) -1.07
C) 13.0
D) 0.0850
E) 1.20 × 10-13

back 93

A

front 94

The pH of an aqueous solution at 25.0 °C is 10.55. What is the molarity of H+ in this solution?
A) 2.8 × 10-11
B) 3.5 × 10-4
C) 3.45
D) 1.1 × 10-13
E) 3.5 × 1010

back 94

A

front 95

Calculate the molarity of hydroxide ion in an aqueous solution that has a pOH of 3.00.
A) 1.0 × 10-3
B) 11.00
C) 1.0 × 10-11
D) 3.0 × 10-14
E) 1.1 × 10-13

back 95

A

front 96

What is the pH of an aqueous solution at 25.0 °C in which [H+] is 0.0015 M?
A) 6.50
B) 2.82
C) -2.82
D) -6.50
E) none of the above

back 96

B

front 97

What is the pOH of an aqueous solution at 25.0 °C in which [H+] is 0.0050 M?
A) 8.70
B) 11.70
C) -11.70
D) -8.70
E) none of the above

back 97

B

front 98

What is the pH of an aqueous solution at 25.0 °C in which [OH-] is 0.0030 M?
A) 5.81
B) -11.48
C) 2.52
D) -2.52
E) 11.48

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E

front 99

An aqueous solution of ammonia at 25.0 °C has a [OH-] of 0.0010 M. What is the pOH of the solution?
A) 11.00
B) 3.00
C) -3.00
D) 6.91
E) -11.00

back 99

B

front 100

What is the concentration (in M) of hydronium ions in a solution at 25.0 °C with pH = 4.146?
A) 4.15
B) 9.85
C) 1.40 × 10-10
D) 7.15 × 10-5
E) none of the above

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D

front 101

What is the concentration (in M) of hydroxide ions in a solution at 25.0 °C with pH = 4.282?
A) 4.28
B) 9.72
C) 1.92 × 10-10
D) 5.22 × 10-5
E) none of the above

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C

front 102

An aqueous solution contains 0.10 M HNO3. The solution is ________.
A) acidic
B) basic
C) neutral
D) very dilute
E) highly colored

back 102

A

front 103

Which solution will be the most basic?
A) 0.10 M Ba(OH)2
B) 0.10 M KOH
C) 0.10 M H2O
D) 0.10 M CH3OH
E) All solutions have equal basicity.

back 103

A

front 104

A 1.0 × 10-2 M aqueous solution of at 25.0 °C has a pH of ________.
A) 12.30
B) 1.70
C) 2.0 × 10-2
D) 5.0 × 10-13
E) 12.00

back 104

A

front 105

What is the pH of a 0.030 M aqueous solution of calcium hydroxide?
A) 1.52
B) 12.48
C) 10.41
D) 12.78
E) 1.22

back 105

D

front 106

What is the pOH of a 0.030 M solution of calcium hydroxide?
A) 12.78
B) 1.22
C) 12.48
D) 10.41
E) 1.52

back 106

B

front 107

Hydrochloric acid is a strong acid. This means that ________.
A) HCl dissociates completely to H+(aq) and Cl-(aq) when it dissolves in water
B) HCl does not dissociate at all when it is dissolved in water
C) HCl produces a gaseous product when it is neutralized
D) HCl cannot be neutralized by a weak base
E) aqueous solutions of HCl contain equal concentrations of H+(aq) and OH-(aq)

back 107

A

front 108

The acid-dissociation constant at 25.0 °C for hypochlorous acid (HClO) is 3.0 × 10-8. At equilibrium, the molarity of H3O+ in a 0.066 M solution of HClO is ________.
A) 4.4 × 10-5
B) 0.066
C) 2.2 × 10-10
D) 4.35
E) 1.18

back 108

A

front 109

In which of the following aqueous solutions does the weak acid exhibit the highest percentage ionization?
A) 0.01 M H2SO3 (Ka = 1.4 × 10-2)
B) 0.01 M HCN (Ka = 6.2 × 10-10)
C) 0.01 M H2CO3 (Ka = 4.5 × 10-7)
D) 0.01 M HC3H5O2 (Ka = 1.3 × 10-5)
E) 0.01 M HOCl (Ka = 3.5 × 10-8)

back 109

A

front 110

In which of the following aqueous solutions does the weak acid exhibit the lowest percentage ionization?
A) 0.01 M HCN (Ka = 6.2 × 10-10)
B) 0.01 M H2CO3 (Ka = 4.5 × 10-7)
C) 0.01 M HNO2 (Ka = 4.0 × 10-4)
D) 0.01 M HCHO2 (Ka = 1.8 × 10-4)
E) 0.01 M HOCl (Ka = 3.5 × 10-8)

back 110

A

front 111

The of hypochlorous acid (HClO) is 3.0 × 10-8 at 25.0 °C. Calculate the pH of a 0.0385 M hypochlorous acid solution.
A) 3.05
B) 9.53
C) 4.47
D) 6.52
E) -3.05

back 111

C

front 112

The Ka of hydrofluoric acid (HF) at 25.0 °C is 6.8 × 10-4. What is the pH of a 0.45 M aqueous solution of HF?
A) 4.05
B) 1.76
C) 3.64
D) 0.35
E) 1.41

back 112

B

front 113

The of citric acid is 1.9 × 10-5 at 25.0 °C. What is the pH of a 0.35 M aqueous solution of citric acid?
A) 0.46
B) 2.59
C) 5.23
D) -3.46
E) 2.13

back 113

B

front 114

What is the [H+] (M) of a solution with a concentration of 1.4 x 10-2 M and Kb is 6.4 × 10-4 at 25.0 °C?
A) 3.3 × 10-12
B) 2.7 × 10-3
C) 3.0 × 10-3
D) 3.7 × 10-12
E) 11.43

back 114

D

front 115

Calculate the pH of a 0.500 M aqueous solution of N . The Kb of NH3 is 1.77 x 10-5.
A) 8.95
B) 11.47
C) 2.53
D) 11.77
E) 2.23

back 115

B

front 116

Which of the following 0.5 M aqueous salt solutions will have a pH of 7.0 at 25.0 °C?

LiF, RbBr, NaClO4, NH4Cl

A) LiF only
B) NaClO4 only
C) LiF and RbBr
D) RbBr and NaClO4
E) NH4Cl only

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D

front 117

Which of the following salts will produce a basic solution?
A) Mg(ClO4)2
B) RbBr
C) Na2SO3
D) NH4NO3
E) KNO3

back 117

C

front 118

Which of the following salts will produce an acidic solution?
A) Sr(ClO4)2
B) KBr
C) NH4I
D) K2CO3
E) NaNO3

back 118

C

front 119

Which of the following salts will produce a neutral solution?
A) NaBr
B) LiNO2
C) LiF
D) Na2CO3
E) NH4Cl

back 119

A

front 120

The Ka of some acid, HA, at 25.0 °C is 4.9 × 10-10. What is the pH of a 0.050 M aqueous solution of A-?
A) 1.0 × 10-3
B) 3.00
C) 11.00
D) 9.9 × 10-12
E) 2.5 × 10-11

back 120

C

front 121

The Kb for A- is 4.9 x 10-10. What is the pOH of a 0.0727 M aqueous NaA solution at 25.0 °C?
A) 9.33
B) 5.22
C) 8.78
D) 1.14
E) 10.00

back 121

B

front 122

The Kb for A- is 4.9 x 10-10. What is the pH of a 0.0787 M aqueous NaA solution at 25.0 °C?
A) 9.33
B) 10.00
C) 5.21
D) 1.10
E) 8.79

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E

front 123

The Ka for acid HA is 7.0 x 10-4. What is the pH of a 0.15 M aqueous solution of KA?
A) 0.82
B) 8.17
C) 5.83
D) 1.17
E) 5.01

back 123

B

front 124

The Ka for acid HA is 7.0 x 10-4. What is the pOH of a 0.10 M aqueous solution of KA?
A) 5.92
B) 1.00
C) 8.08
D) 1.58
E) 5.01

back 124

A

front 125

What is the pH of 0.626 M anilinium hydrochloride (C6H5NH3Cl) solution in water, given that Kb for aniline is 3.83 × 10-4?
A) 1.81
B) 5.39
C) 12.19
D) 12.42
E) 8.61

back 125

B

front 126

What is the pOH of 0.606 M anilinium hydrochloride (C6H5NH3Cl) solution in water, given that Kb for aniline is 3.83 × 10-4?
A) 12.42
B) 1.82
C) 8.60
D) 5.40
E) 12.18

back 126

C

front 127

What is the pH of a 0.40 M aqueous solution of NH4Br at 25.0 °C? Kb for NH3 is 1.8 × 10-5.
A) 4.82
B) 2.57
C) 9.18
D) 11.43
E) 11.23

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A

front 128

What is the pOH of a 0.20 M aqueous solution of N Br at 25.0 °C? Kb for NH3 is 1.8 × 10-5.
A) 2.72
B) 4.98
C) 11.28
D) 11.23
E) 9.02

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E

front 129

The Ka for formic acid (HCO2H) is 1.8 × 10-4. What is the pH of a 0.20 M aqueous solution of sodium formate (NaHCO2)?
A) 11.64
B) 5.48
C) 3.39
D) 8.52
E) 4.26

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D

front 130

Of the following, which is the strongest acid?
A) HIO4
B) HIO3
C) HIO2
D) HIO
E) The acid strength of all of the above is the same.

back 130

A

front 131

Of the following, which is the weakest acid?
A) HPO3-
B) H3PO4
C) H2PO4-
D) HPO4-
E) The acid strength of all of the above is the same.

back 131

A

front 132

The pH of a 0.25 M aqueous solution of HA at 25.0 °C is 4.48. What is the value of Ka for HA?

back 132

4.4 × 10-9

front 133

The pOH of a 0.25 M aqueous solution of HA at 25.0 °C is 9.52. What is the value of Ka for HA?

back 133

4.4 × 10-9

front 134

A 0.045 M solution of ammonia is 2.0% ionized at 25.0 °C. The Kb at 25.0 °C for ammonia is ________.

back 134

1.8 × 10-5

front 135

What is the pH of a sodium fluoride solution prepared by adding 0.4198 grams of sodium fluoride to 100.0 ml of water at 25.0 °C? The Ka at 25.0 °C for HF is 7.2 × 10-4.

back 135

8.07

front 136

What is the pOH of a sodium fluoride solution prepared by adding 0.4198 grams of sodium fluoride to 100.0 ml of water at 25.0 °C? The Ka at 25.0 °C for HF is 7.2 × 10-4.

back 136

5.93

front 137

In the reaction

BF3 + F- → BF4-

BF3 acts as a Br∅nsted-Lowry acid.

back 137

false

front 138

An acid containing the COOH group is called a carbo-oxy acid.

back 138

false

front 139

A Lewis acid is an electron-pair acceptor, and a Lewis base is an electron-pair donor.

back 139

true